tert-Butyl-dimethyl-((E)-5-phenylsulfanyl-pent-3-enyloxy)-silane

Base Information

• Chemical Name: tert-Butyl-dimethyl-((E)-5-phenylsulfanyl-pent-3-enyloxy)-silane
• CAS No.: 114678-60-3
• Molecular Formula: C₁₇H₂₈OSSi
• Molecular Weight: 308.56
• Mol file: 114678-60-3.mol

Synonyms:tert-Butyl-dimethyl-((E)-5-phenylsulfanyl-pent-3-enyloxy)-silane

Chemical Property of tert-Butyl-dimethyl-((E)-5-phenylsulfanyl-pent-3-enyloxy)-silane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tert-Butyl-dimethyl-((E)-5-phenylsulfanyl-pent-3-enyloxy)-silane

There total 2 articles about tert-Butyl-dimethyl-((E)-5-phenylsulfanyl-pent-3-enyloxy)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

tert-butyldimethylsilyl chloride (18162-48-6) + 5-(phenylthio)pent-3-en-1-ol (114678-57-8) → tert-Butyl-dimethyl-((E)-5-phenylsulfanyl-pent-3-enyloxy)-silane (114678-60-3)

Guidance literature:

With N,N,N,N,-tetramethylethylenediamine; In dichloromethane; for 1.5h;

DOI:10.1021/ja00224a029

Reference yield:

1-hydroxy-3-(phenylthio)-4-pentene (84132-31-0) → tert-Butyl-dimethyl-((E)-5-phenylsulfanyl-pent-3-enyloxy)-silane (114678-60-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 93 percent / CH₂Cl₂ / 12 h / Irradiation

2: 76 percent / tetramethylethylenediamine / CH₂Cl₂ / 1.5 h

With N,N,N,N,-tetramethylethylenediamine; In dichloromethane;

DOI:10.1021/ja00224a029

Reference yield:

tert-Butyl-dimethyl-((E)-5-phenylsulfanyl-pent-3-enyloxy)-silane (114678-60-3) → 5-(phenylsulfinyl)pent-3-enyl dimethyl(1,1-dimethylethyl)silyl ether (114678-61-4,114678-62-5)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -70 ℃;

DOI:10.1021/ja00224a029

upstream raw materials:

tert-butyldimethylsilyl chloride

5-(phenylthio)pent-3-en-1-ol

1-hydroxy-3-(phenylthio)-4-pentene

Downstream raw materials:

5-(phenylsulfinyl)pent-3-enyl dimethyl(1,1-dimethylethyl)silyl ether

(1'RS,2'E,3RS,R_SS_S)-3-<1'-<2''-ethyl>-3'-(phenylsulfinyl)-prop-2'-enyl>cyclopentanone