1-(Bromomethyl)-4-chloro-2-methylbenzene

Base Information

Chemical Name:1-(Bromomethyl)-4-chloro-2-methylbenzene
CAS No.:122488-73-7
Molecular Formula:C₈H₈BrCl
Molecular Weight:219.509
Hs Code.:
European Community (EC) Number:821-787-4

Synonyms:122488-73-7;1-(BROMOMETHYL)-4-CHLORO-2-METHYLBENZENE;Benzene, 1-(bromomethyl)-4-chloro-2-methyl-;4-chloro-2-methylbenzyl bromide;SCHEMBL2796665;YKNWZHYCHLFKGW-UHFFFAOYSA-N;1-Bromomethyl-4-chloro-2-methyl-benzene;Benzene,1-(bromomethyl)-4-chloro-2-methyl-;FT-0710964;EN300-729605

Suppliers and Price of 1-(Bromomethyl)-4-chloro-2-methylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
1-(Bromomethyl)-4-chloro-2-methylbenzene
100mg
$ 240.00

Labseeker
1-(bromomethyl)-4-chloro-2-methylbenzene 95
5g
$ 1467.00

American Custom Chemicals Corporation
1-(BROMOMETHYL)-4-CHLORO-2-METHYLBENZENE 95.00%
5MG
$ 502.49

Alichem
4-Chloro-2-methylbenzylbromide
250mg
$ 489.60

Alichem
4-Chloro-2-methylbenzylbromide
500mg
$ 839.45

Alichem
4-Chloro-2-methylbenzylbromide
1g
$ 1490.00

AK Scientific
1-(Bromomethyl)-4-chloro-2-methylbenzene
5g
$ 1381.00

AK Scientific
1-(Bromomethyl)-4-chloro-2-methylbenzene
1g
$ 542.00

AK Scientific
1-(Bromomethyl)-4-chloro-2-methylbenzene
500mg
$ 409.00

Total 2 raw suppliers

Chemical Property of 1-(Bromomethyl)-4-chloro-2-methylbenzene

Chemical Property:

XLogP3:4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:217.94979
Heavy Atom Count:10
Complexity:105

Purity/Quality:

98%+ ^*data from raw suppliers

1-(Bromomethyl)-4-chloro-2-methylbenzene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=C(C=CC(=C1)Cl)CBr

Technology Process of 1-(Bromomethyl)-4-chloro-2-methylbenzene

There total 3 articles about 1-(Bromomethyl)-4-chloro-2-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 129716-11-6
2-methyl-4-chlorobenzyl alcohol

: 122488-73-7
1-(bromomethyl)-4-chloro-2-methylbenzene

Guidance literature:: With phosphorus tribromide; In diethyl ether; at 20 ℃;

Reference yield:

: 7499-07-2
4-chloro-2-methylbenzoic acid

: 122488-73-7
1-(bromomethyl)-4-chloro-2-methylbenzene

Guidance literature:: Multi-step reaction with 2 steps

1: diborane / tetrahydrofuran / 1.5 h / 0 °C

2: PBr₃ / toluene / 0.17 h / 100 °C

With phosphorus tribromide; diborane; In tetrahydrofuran; toluene;
DOI:10.1021/jm00128a016

Reference yield:

: 615-60-1
4-chloro-1,2-dimethylbenzene

: 869721-21-1
5-chloro-2-methyl-benzyl bromide

: 122488-73-7
1-(bromomethyl)-4-chloro-2-methylbenzene

Guidance literature:: With ammonium cerium(IV) nitrate; sodium bromide; In acetic acid; at 60 ℃; Product distribution; Mechanism; Other investigated halogenating systems: Co(OAc)3/NaBr, Br2/hν, NBS, Na2S2O8/NaBr, CAN/LiCl, Co(OAc)3/LiCl, Cl2/hν and Cl2/hν in CCl4. Comparative investigation of oxidation with CAN and Co(OAc)3.;
DOI:10.1016/S0040-4020(01)89841-0