Dichlorobis(trimethylsilyl-pi-cyclopentadienyl)titanium

Base Information

Chemical Name:Dichlorobis(trimethylsilyl-pi-cyclopentadienyl)titanium
CAS No.:59307-41-4
Molecular Formula:C16H26Cl2Si2Ti
Molecular Weight:393.339
Hs Code.:

Synonyms:Dichlorobis(trimethylsilyl-pi-cyclopentadienyl)titanium;Titanium, dichlorobis(trimethylsilyl-pi-cyclopentadienyl)-;Bis(eta(sup 5)-trimethylsilylcyclopentadienyl)dichlorotitan(IV) [German];Bis(eta(sup 5)-trimethylsilylcyclopentadienyl)dichlorotitan(IV);59307-41-4;C16H26Cl2Si2Ti;C16-H26-Cl2-Si2-Ti;LS-153904

Suppliers and Price of Dichlorobis(trimethylsilyl-pi-cyclopentadienyl)titanium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Dichlorobis(trimethylsilyl-pi-cyclopentadienyl)titanium

Chemical Property:

Vapor Pressure:4.95mmHg at 25°C
Boiling Point:150.2°C at 760 mmHg
Flash Point:29.7°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:392.042950
Heavy Atom Count:21
Complexity:85.2

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C1=C[CH-]C=C1.C[Si](C)(C)C1=C[CH-]C=C1.[Cl-].[Cl-].[Ti+4]

Technology Process of Dichlorobis(trimethylsilyl-pi-cyclopentadienyl)titanium

There total 4 articles about Dichlorobis(trimethylsilyl-pi-cyclopentadienyl)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1270-98-0
cyclopentadienyl titanium(IV) trichloride

: 1271-19-8
bis(cyclopentadienyl)titanium dichloride

: 59307-41-4
bis(η5-trimethylsilylcyclopentadienyl)titanium(IV)dichloride

: 79269-70-8
dichloro(η⁵-cyclopentadienyl)[η⁵-(trimethylsilyl)cyclopentadienyl]titanium

Guidance literature:: With C₅H₅SiMe₃; C₄H₉Li; In tetrahydrofuran; hexane; under N2; adding 2.5 M nBuLi in hexane to THF soln. of C5H5SiMe3 at -70°C, stirring for 5 min, warming within 1 h to 25°C, heatingto reflux for 5 min, cooling to 25°C, adding THF soln. of (C5H5) TiCl3, heating to reflux for 1 h; removal of volatiles in oil pump vac., extg. residue with CH2Cl2, filtering through SiO2, removal of solvents in oil pump vac.; elem. anal.;
DOI:10.1016/S0022-328X(01)01000-2

Reference yield: 40.0%

: bis(η5-trimethylsilyl-cyclopentadienyl)bis(phenylethinyl)-titanium

: copper dichloride

: 59307-41-4
bis(η5-trimethylsilylcyclopentadienyl)titanium(IV)dichloride

: [(η(5)-C5H4SiMe3)2Ti(C.tplbond.CPh)2]CuCl

: 886-66-8
1,4-diphenyl-1,3-butadiyne

Guidance literature:: In tetrahydrofuran; byproducts: (CuCl)(n); under N2; soln. of CuCl2 in THF at 25°C mixed with equimolar amt. of Ti complex in THF; stirred at 25°C for 2 h; filtered through Kieselgur; volatiles removed in vac.; sepd. by chromy.(Kieselgel, -20°C, n-pentane);
DOI:10.1016/S0022-328X(00)00067-X

Reference yield: 40.0%

: (η(5)-C5H4SiMe3)2Ti(C.tplbond.CPh)(C.tplbond.CSiMe3)

: copper dichloride

: 59307-41-4
bis(η5-trimethylsilylcyclopentadienyl)titanium(IV)dichloride

: (η(5)-C5H4SiMe3)2Ti(C.tplbond.CPh)(C.tplbond.CSiMe3)CuCl

: 38177-56-9
trimethyl(4-phenylbuta-1,3-diyn-1-yl)silane

Guidance literature:: In tetrahydrofuran; byproducts: (CuCl)(n); under N2; soln. of CuCl2 in THF at 25°C mixed with equimolar amt. of Ti complex in THF; stirred at 25°C for 2 h; filtered through Kieselgur; volatiles removed in vac.; sepd. by chromy.(Kieselgel, -20°C, n-pentane);
DOI:10.1016/S0022-328X(00)00067-X