Silane, trimethyl(4-phenyl-1,3-butadiynyl)-

Base Information

• Chemical Name: Silane, trimethyl(4-phenyl-1,3-butadiynyl)-
• CAS No.: 38177-56-9
• Molecular Formula: C13H14Si
• Molecular Weight: 198.34
• DSSTox Substance ID: DTXSID10451701
• Nikkaji Number: J893.309J
• Wikidata: Q82271858
• Mol file: 38177-56-9.mol

Synonyms:Silane, trimethyl(4-phenyl-1,3-butadiynyl)-;38177-56-9;DTXSID10451701;(4-Phenyl-1,3-butadiynyl)trimethylsilane

Chemical Property of Silane, trimethyl(4-phenyl-1,3-butadiynyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 198.086476981
• Heavy Atom Count: 14
• Complexity: 301

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C#CC#CC1=CC=CC=C1

Technology Process of Silane, trimethyl(4-phenyl-1,3-butadiynyl)-

There total 29 articles about Silane, trimethyl(4-phenyl-1,3-butadiynyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

phenylethynyl(phenyl)-λ3-iodane tetrafluoroborate + trimethylsilylacetylene (1066-54-2) → trimethyl(4-phenylbuta-1,3-diyn-1-yl)silane (38177-56-9)

Guidance literature:

With sodium hydrogencarbonate; palladium diacetate; In water; acetonitrile; for 0.166667h; Ambient temperature;

DOI:10.1039/cc9960000835

Reference yield: 91.0%

1,4-bis(trimethylsilyl)-1,3-butadiyne (4526-07-2) + 1,4-diphenyl-1,3-butadiyne (886-66-8) → trimethyl(4-phenylbuta-1,3-diyn-1-yl)silane (38177-56-9)

Guidance literature:

With C₄₀H₈₀O₁₁Si₃W; In dichloromethane; at 20 ℃;

DOI:10.1002/chem.201801651

Reference yield: 91.0%

1-iodo-2-phenylethyne (932-88-7) + trimethylsilylacetylene (1066-54-2) → trimethyl(4-phenylbuta-1,3-diyn-1-yl)silane (38177-56-9)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; In tetrahydrofuran; for 0.25h; Ambient temperature;

DOI:10.1080/00397919108019785

upstream raw materials:

(2-bromoethynyl)trimethylsilane

phenylacetylene

chloro-trimethyl-silane

buta-1,3-diynylbenzene

Downstream raw materials:

C₁₄H₁₄O

cis-1-phenyl-4-trimethylsilyl-1-buten-3-yne

2-deuterio-(Z)-phenyl-4-trimethylsilyl-1-buten-3-yne

2-deuterio-(E)-phenyl-4-trimethylsilyl-1-buten-3-yne