Benzoic acid (1S,2S,3R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methanesulfonyloxy-1-methyl-hex-5-enyl ester

Base Information

Chemical Name:Benzoic acid (1S,2S,3R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methanesulfonyloxy-1-methyl-hex-5-enyl ester
CAS No.:97971-25-0
Molecular Formula:C₃₁H₃₈O₆SSi
Molecular Weight:566.791
Hs Code.:

Synonyms:Benzoic acid (1S,2S,3R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methanesulfonyloxy-1-methyl-hex-5-enyl ester

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Chemical Property of Benzoic acid (1S,2S,3R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methanesulfonyloxy-1-methyl-hex-5-enyl ester

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Technology Process of Benzoic acid (1S,2S,3R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methanesulfonyloxy-1-methyl-hex-5-enyl ester

There total 5 articles about Benzoic acid (1S,2S,3R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methanesulfonyloxy-1-methyl-hex-5-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 124-63-0
methanesulfonyl chloride

: 97971-24-9
(2S,3S,4R)-2-benzoyloxy-4-(tert-butyldiphenylsilyloxy)-hept-6-en-3-ol

: 97971-25-0
Benzoic acid (1S,2S,3R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methanesulfonyloxy-1-methyl-hex-5-enyl ester

Guidance literature:: With pyridine; In dichloromethane; Ambient temperature;
DOI:10.1016/0008-6215(85)85190-9

Reference yield:

: 89084-40-2
(2S,3S,4R)-2,3-isopropylidenedioxy-4-(tert-butyldiphenylsilyloxy)-hept-6-ene

: 97971-25-0
Benzoic acid (1S,2S,3R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methanesulfonyloxy-1-methyl-hex-5-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / aq. acetic acid / acetonitrile / 6 h

2: 80 percent / pyridine / CH₂Cl₂ / Ambient temperature

3: 95 percent / pyridine / CH₂Cl₂ / Ambient temperature

With pyridine; acetic acid; In dichloromethane; acetonitrile;
DOI:10.1016/0008-6215(85)85190-9

Reference yield:

: 85273-19-4
(2S,3S,4R)-2,3-isopropylidenedioxyhept-6-en-4-ol

: 97971-25-0
Benzoic acid (1S,2S,3R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methanesulfonyloxy-1-methyl-hex-5-enyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / imidazole / dimethylformamide / 16 h / Ambient temperature

2: 90 percent / aq. acetic acid / acetonitrile / 6 h

3: 80 percent / pyridine / CH₂Cl₂ / Ambient temperature

4: 95 percent / pyridine / CH₂Cl₂ / Ambient temperature

With pyridine; 1H-imidazole; acetic acid; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/0008-6215(85)85190-9