methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-hydroxybenzoate

Base Information

Chemical Name:methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-hydroxybenzoate
CAS No.:1142225-71-5
Molecular Formula:C₁₄H₁₈O₃
Molecular Weight:234.295
Hs Code.:

Synonyms:methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-hydroxybenzoate

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Chemical Property of methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-hydroxybenzoate

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Technology Process of methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-hydroxybenzoate

There total 7 articles about methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-hydroxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.5%

: 1142225-69-1
methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-(tetrahydro-2H-pyran-2-yloxy)benzoate

: 1142225-71-5
methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-hydroxybenzoate

Guidance literature:: With pyridinium p-toluenesulfonate; In methanol; at 23 - 60 ℃;

Reference yield:

: 75-97-8
3,3-dimethyl-butan-2-one

: 1142225-71-5
methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-hydroxybenzoate

Guidance literature:: Multi-step reaction with 4 steps

1.1: lithium diisopropyl amide / tetrahydrofuran / -78 °C

1.2: -78 - 20 °C

2.1: potassium phenolate / bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine / toluene / 3.5 h / 50 °C / Inert atmosphere

3.1: potassium phosphate / 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl; palladium diacetate / water; N,N-dimethyl-formamide / 19 h / 70 °C / Inert atmosphere

4.1: pyridinium p-toluenesulfonate / methanol / 19 h / 23 - 60 °C

With potassium phosphate; potassium phenolate; pyridinium p-toluenesulfonate; lithium diisopropyl amide; bis-triphenylphosphine-palladium(II) chloride; 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl; palladium diacetate; triphenylphosphine; In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide; toluene; 3.1: Suzuki Coupling;

Reference yield:

: 27701-32-2
3,3-dimethyl-1-butenyl-2-triflate

: 1142225-71-5
methyl 3-(1-(1,1-dimethylethyl)ethenyl)-4-hydroxybenzoate

Guidance literature:: Multi-step reaction with 3 steps

1: potassium phenolate / bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine / toluene / 3.5 h / 50 °C / Inert atmosphere

2: potassium phosphate / 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl; palladium diacetate / water; N,N-dimethyl-formamide / 19 h / 70 °C / Inert atmosphere

3: pyridinium p-toluenesulfonate / methanol / 19 h / 23 - 60 °C

With potassium phosphate; potassium phenolate; pyridinium p-toluenesulfonate; bis-triphenylphosphine-palladium(II) chloride; 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl; palladium diacetate; triphenylphosphine; In methanol; water; N,N-dimethyl-formamide; toluene; 2: Suzuki Coupling;