benzoic acid 1-hexylvinyl ester

Base Information

• Chemical Name: benzoic acid 1-hexylvinyl ester
• CAS No.: 107820-40-6
• Molecular Formula: C₁₅H₂₀O₂
• Molecular Weight: 232.323
• Mol file: 107820-40-6.mol

Synonyms:benzoic acid 1-hexylvinyl ester

Chemical Property of benzoic acid 1-hexylvinyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of benzoic acid 1-hexylvinyl ester

There total 8 articles about benzoic acid 1-hexylvinyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

n-octyne (629-05-0) + benzoic acid (65-85-0,8013-63-6) → benzoic acid 1-hexylvinyl ester (107820-40-6)

Guidance literature:

With C₅₈H₃₄F₁₈O₆P₂Ru; silver trifluoromethanesulfonate; In toluene; at 70 ℃; for 3h; regioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.joc.5b02293

Reference yield: 82.0%

n-octyne (629-05-0) + benzoic acid (65-85-0,8013-63-6) → benzoic acid 1-hexylvinyl ester (107820-40-6) + benzoic acid 1-octenyl ester

Guidance literature:

With lithium carbonate; phosphorous acid trimethyl ester; bis(1,5-cyclooctadiene)diiridium(I) dichloride; In toluene; at 100 ℃; for 15h; Further Variations:; Reagents; Catalysts; time; Product distribution;

DOI:10.1016/S0040-4039(02)02451-6

Reference yield: 80.0%

n-octyne (629-05-0) + benzoic acid (65-85-0,8013-63-6) → 3-(1-octen)-yl benzoate (52513-06-1) + benzoic acid 1-hexylvinyl ester (107820-40-6)

Guidance literature:

With chloro(1,5-cyclooctadiene)rhodium(I) dimer; bis[2-(diphenylphosphino)phenyl] ether; In 1,2-dichloro-ethane; at 70 ℃; for 16h; chemoselective reaction; Inert atmosphere;

DOI:10.1021/ja1108613

upstream raw materials:

n-octyne

benzoic acid

Downstream raw materials:

oct-2-en-2-yl benzoate

(R)-benzoic acid 1-methylheptyl ester

(S)-benzoic acid 1-methylheptyl ester

(R)-Octan-2-ol