52513-06-1Relevant articles and documents
The first synthesis of threo- and erythro-(E)-4,5-dihydroxydec-2-enals carbonyls related to the peroxidation of liver microsomal lipids
Allevi, Pietro,Cajone, Francesco,Ciuffreda, Pierangela,Anastasia, Mario
, p. 1347 - 1350 (1995)
The first synthesis of threo and erythro (E)-4,5-dihydroxydec-2-enals, aldehydes related to the lipid peroxidation is accomplished by reaction of α-benzoyloxheptanal with the Grignard reagent of 3,3-diethoxy-1-propyne and lithium aluminium hydride reducti
Copper-catalyzed regioselective allylic oxidation of olefins via C–H activation
Zhu, Nengbo,Qian, Bo,Xiong, Haigen,Bao, Hongli
supporting information, p. 4125 - 4128 (2017/09/29)
A regioselective oxidation of allylic C–H bond to C–O bond catalyzed by copper (I) was developed with diacyl peroxides as oxidants. The oxidation of allylic C–H bond was accomplished with good yield and regioselectivity under mild reaction conditions. This method has a broad substrate scope including cyclic olefins, terminal and internal acyclic olefins and allyl benzene compounds. The reaction proceeds by a radical mechanism as suggested by spin trapping experiments.
Mechanistic investigations of the rhodium catalyzed propargylic CH activation
Gellrich, Urs,Meissner, Antje,Steffani, Alberto,Kaehny, Matthias,Drexler, Hans-Joachim,Heller, Detlef,Plattner, Dietmar A.,Breit, Bernhard
supporting information, p. 1097 - 1104 (2014/02/14)
Previously we reported the redox-neutral atom economic rhodium catalyzed coupling of terminal alkynes with carboxylic acids using the DPEphos ligand. We herein present a thorough mechanistic investigation applying various spectroscopic and spectrometric m
