tetraphenylphosphonium dioxotrichlororuthenate(VI)

Base Information

Chemical Name:tetraphenylphosphonium dioxotrichlororuthenate(VI)
CAS No.:91528-99-3
Molecular Formula:C₂₄H₂₀P*Cl₃O₂Ru
Molecular Weight:578.824
Hs Code.:

Synonyms:tetraphenylphosphonium dioxotrichlororuthenate(VI)

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Chemical Property of tetraphenylphosphonium dioxotrichlororuthenate(VI)

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Technology Process of tetraphenylphosphonium dioxotrichlororuthenate(VI)

There total 1 articles about tetraphenylphosphonium dioxotrichlororuthenate(VI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: ruthenium(IV) oxide

: 2001-45-8
tetraphenyl phosphonium chloride

: 91528-99-3
tetraphenylphosphonium dioxotrichlororuthenate(VI)

Guidance literature:: With hydrogenchloride; potassium hydroxide; sodium periodate; In tetrachloromethane; water; RuO2 in H2O stirred with NaIO4, extn. (CCl4), shaken with aq. KOH, sepd. ruthenate soln. cooled to 0°C, pptn. upon addn. of a satd. (PPh4)Cl soln. and aq. HCl; filtered, ppt. dried in vac., recrystn. by pptn. from CH2Cl2 with hexane, elem.anal.;

Reference yield: 30.0%

: 91528-99-3
tetraphenylphosphonium dioxotrichlororuthenate(VI)

: 1609-86-5
Tert-butyl isocyanate

: tetraphenylphosphonium dichloro(N,N'-di-tert-butylureato-κ(2)N,N')nitridoruthenate(VI)

Guidance literature:: In acetonitrile; byproducts: CO2, HCl, isobutylene; excess t-BuNCO, refluxing (3 h);; filtration, evapn., recrystn. (CH2Cl2/Et2O/hexane); elem anal.;;
DOI:10.1039/DT9910002791