Technology Process of 4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)benzyl bromide
There total 1 articles about 4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)benzyl bromide which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
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1338932-14-1
4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)benzyl alcohol
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1338932-16-3
4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)benzyl bromide
- Guidance literature:
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With
carbon tetrabromide; triphenylphosphine;
In
dichloromethane;
at 20 ℃;
for 1h;
DOI:10.1016/j.tet.2011.08.087
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1338932-16-3
4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)benzyl bromide
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1338932-18-5
3-O-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)benzyl]-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
- Guidance literature:
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1,2:5,6-di-O-isopropylidene-α-D-glucofuranose;
With
sodium hydride;
In
tetrahydrofuran; paraffin oil;
at 0 ℃;
for 0.5h;
Inert atmosphere;
4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)benzyl bromide;
With
tetra-(n-butyl)ammonium iodide;
In
tetrahydrofuran; paraffin oil;
at 0 - 20 ℃;
for 16h;
Inert atmosphere;
DOI:10.1016/j.tet.2011.08.087
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1338932-16-3
4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)benzyl bromide
- Guidance literature:
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Multi-step reaction with 2 steps
1.1: sodium hydride / tetrahydrofuran; paraffin oil / 0.5 h / 0 °C / Inert atmosphere
1.2: 16 h / 0 - 20 °C / Inert atmosphere
2.1: water; trifluoroacetic acid / dichloromethane / 5 h / 20 °C
With
water; sodium hydride; trifluoroacetic acid;
In
tetrahydrofuran; dichloromethane; paraffin oil;
DOI:10.1016/j.tet.2011.08.087
