Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

Base Information

Chemical Name:Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate
CAS No.:111437-04-8
Molecular Formula:C₅₈H₇₆O₁₃Si
Molecular Weight:1009.32
Hs Code.:

Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'-<cyclohexylidenebis(oxy)>-4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

Synonyms:Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

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Chemical Property of Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

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Technology Process of Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

There total 3 articles about Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 111436-93-2
Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

: 111437-04-8
Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

Guidance literature:: With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide; Yield given. Multistep reaction; 1.) THF, 23 deg C, 2 h, 2.) 23 deg C, 2 h;
DOI:10.1021/ja00190a036

Reference yield:

: 3587-60-8
Benzyloxymethyl chloride

: 111437-04-8
Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH / THF, DMF, 1.) room temp, 20 min, 2.) 1 h

2: 1.) 0.5 M 9-BBN, 2.) 3 M aq. NaOH, 30percent H₂O₂ / 1.) THF, 23 deg C, 2 h, 2.) 23 deg C, 2 h

With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide; sodium hydride;
DOI:10.1021/ja00190a036

Reference yield:

: 111436-92-1
methyl 6,8-bis<(benzyloxy)methoxy>-1-hydroxy-3-<(2'R,3'S,4'R,5'S,6'R)-3'-methoxy-5',6'-(cyclohexylidenedioxy)-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>naphthoate

: 111437-04-8
Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH / THF, DMF, 1.) room temp, 20 min, 2.) 1 h

2: 1.) 0.5 M 9-BBN, 2.) 3 M aq. NaOH, 30percent H₂O₂ / 1.) THF, 23 deg C, 2 h, 2.) 23 deg C, 2 h

With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide; sodium hydride;
DOI:10.1021/ja00190a036