111436-92-1

Basic information

• Product Name: methyl 6,8-bis<(benzyloxy)methoxy>-1-hydroxy-3-<(2'R,3'S,4'R,5'S,6'R)-3'-methoxy-5',6'-(cyclohexylidenedioxy)-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>naphthoate
• Synonyms: methyl 6,8-bis<(benzyloxy)methoxy>-1-hydroxy-3-<(2'R,3'S,4'R,5'S,6'R)-3'-methoxy-5',6'-(cyclohexylidenedioxy)-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>naphthoate
• CAS NO: 111436-92-1
• Molecular Weight: 871.153
• Mol File: 111436-92-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 6,8-bis<(benzyloxy)methoxy>-1-hydroxy-3-<(2'R,3'S,4'R,5'S,6'R)-3'-methoxy-5',6'-(cyclohexylidenedioxy)-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>naphthoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6,8-bis<(benzyloxy)methoxy>-1-hydroxy-3-<(2'R,3'S,4'R,5'S,6'R)-3'-methoxy-5',6'-(cyclohexylidenedioxy)-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>naphthoate(111436-92-1)
• EPA Substance Registry System: methyl 6,8-bis<(benzyloxy)methoxy>-1-hydroxy-3-<(2'R,3'S,4'R,5'S,6'R)-3'-methoxy-5',6'-(cyclohexylidenedioxy)-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>naphthoate(111436-92-1)

Safety Data

• Hazardous Substances Data: 111436-92-1(Hazardous Substances Data)

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 111436-90-9 Methyl 5(R),6(S),7(R),8(S),9(R)-6-methoxy-8,9-dihydroxy-7-<(tert-butyldimethylsilyl)oxy>-5-vinyldec-2(E)-enoate 8,9-cyclohexyl ketal 
• 111436-91-0 5,7-Bis-benzyloxymethoxy-3H-isobenzofuran-1-one 
• 3587-60-8 Benzyloxymethyl chloride 
• 144107-96-0 methyl 4-<(benzyloxy)methoxy>-6-<(5'S,6'R,7'S,8'R)-6'-<(tert-butyldimethylsilyl)oxy>-7',8'-(cyclohexylidenedioxy)-5'-methoxy-2'-oxonon-3'(E)-enyl>-2-hydroxybenzoate 
• 120264-57-5 (3,5-Bis-benzyloxymethoxy-2-bromo-phenyl)-methanol 
• 120264-55-3 3,5-Bis-benzyloxymethoxy-benzoic acid methyl ester 
• 120264-56-4 (3,5-Bis-benzyloxymethoxy-phenyl)-methanol 
• 111436-89-6 (E)-(4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-5-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-pent-2-enal 
• 111437-03-7 3(R),4(S),5(R),6(S),7(R)-4-Methoxy-6,7-dihydroxy-5-<(tert-butyldimethylsilyl)oxy>-3-vinyloctanal 6.7-cyclohexyl ketal 
• 2150-44-9 1-carbomethoxy-3,5-dihydroxybenzene 

Downstream Products

• 6680-06-4 olivin 
• 111468-56-5 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--2'-<(carbomethoxymethyl)-4'-<(tert-butyldimethylsilyl)oxy>heptyl>>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 111436-96-5 (R)-6,8,9-Tris-benzyloxymethoxy-3-[(1S,2R)-2-hydroxy-1-methoxy-2-((2R,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-3,4-dihydro-2H-anthracen-1-one 
• 111436-97-6 (R)-6,8,9-Tris-benzyloxymethoxy-3-[(S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-2-oxo-ethyl]-3,4-dihydro-2H-anthracen-1-one 
• 111436-95-4 (R)-6,8,9-Tris-benzyloxymethoxy-3-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-3,4-dihydro-2H-anthracen-1-one 
• 111436-99-8 (2S,3S)-6,8,9-Tris-benzyloxymethoxy-2-(tert-butyl-dimethyl-silanyloxy)-3-[(S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-2-oxo-ethyl]-3,4-dihydro-2H-anthracen-1-one 
• 120264-60-0 6,8,9-Tris-benzyloxymethoxy-3-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-1-oxo-1,2,3,4-tetrahydro-anthracene-2-carboxylic acid methyl ester 
• 111436-99-8 3-<1'-<<1'(S),2'(R),3'(S),4'(R)>-3',4'--1'-methoxy-2'-oxopentyl>>-6,8,9-tris<(benzyloxy)methoxy>-1,2,3,4-tetrahydro-2-<(tert-butyldimethylsilyl)oxy>-1(2H)-anthracenone 
• 111437-04-8 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 111436-94-3 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--2'-(2-oxoethyl)-4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 111436-95-4 3-<1'-<<1'(S),2'(R),3'(S),4'(R)>-3',4'--1'-methoxy-2'-<(tert-butyldimethylsilyl)oxy>pentyl>>-6,8,9-tris<(benzyloxy)methoxy>-1,2,3,4-tetrahydro-1(2H)-anthracenone 
• 111436-97-6 3-<1'-<<1'(S),2'(R),3'(S),4'(R)>-3',4'--1'-methoxy-2'-oxopentyl>>-6,8,9-tris<(benzyloxy)methoxy>-1,2,3,4-tetrahydro-1(2H)-anthracenone 
• 111436-96-5 3-<1'-<<1'(S),2'(R),3'(S),4'(R)>-3',4'--2'-hydroxy-1'-methoxypentyl>>-6,8,9-tris<(benzyloxy)methoxy>-1,2,3,4-tetrahydro-1(2H)-anthracenone 
• 6680-06-4 (+) Olivin 

Relevant articles and documents

An Improved Synthesis of Naphthoate Precursors to Olivin

An improved synthesis of olivin synthetic intermediate 3 is described.The synthesis involves the Horner-Wadsworth-Emmons coupling of 14 and 16, the diastereoselective vinylcuprate addition to enone 20, and the condensation of isocoumarin 25 and methyl acetate.A parallel sequence starting from allyl ether 26 has provided naphthoate 35 that is suitably differentiated for glycosylation studies.

A Highly Stereoselective Total Synthesis of the Natural Enantiomer of Olivin

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