3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

Base Information

Chemical Name:3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside
CAS No.:1448452-88-7
Molecular Formula:C₄₁H₄₇N₃O₉
Molecular Weight:725.839
Hs Code.:

Synonyms:3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

Suppliers and Price of 3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

There total 13 articles about 3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 1448453-03-9
3-azidopropyl 3,5-O-di-benzyl-2-O-2-naphthylmethyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

: 1448452-88-7
3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In methanol; dichloromethane; at 20 ℃; for 4h; Inert atmosphere;
DOI:10.1039/c3ob40958a

Reference yield:

: 913060-78-3
phenyl 3,5-O-(di-tert-butylsilanediyl)-1-thio-α-L-arabinofuranoside

: 1448452-88-7
3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

Guidance literature:: Multi-step reaction with 10 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 3 h / 0 °C / Inert atmosphere

2.1: dichloromethane / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

2.2: 0.25 h / -40 - 20 °C / Molecular sieve; Inert atmosphere

3.1: sodium azide / N,N-dimethyl-formamide / 16 h / 60 °C / Inert atmosphere

4.1: pyridine; pyridine hydrogenfluoride / dichloromethane / 2 h / 0 °C / Inert atmosphere

5.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 2 h / 0 °C / Inert atmosphere

6.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; methanol / 3 h / 20 °C / Inert atmosphere

7.1: dichloromethane / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

7.2: 0.25 h / -40 - 20 °C / Molecular sieve; Inert atmosphere

8.1: pyridine hydrogenfluoride / Inert atmosphere

9.1: sodium hydride / N,N-dimethyl-formamide / Inert atmosphere

10.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; methanol / 4 h / 20 °C / Inert atmosphere

With pyridine; sodium azide; sodium hydride; pyridine hydrogenfluoride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In methanol; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1039/c3ob40958a

Reference yield:

: 1448452-68-3
phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside

: 1448452-88-7
3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: pyridine; pyridine hydrogenfluoride / dichloromethane / 2 h / 0 °C / Inert atmosphere

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 2 h / 0 °C / Inert atmosphere

3.1: dichloromethane / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

3.2: 0.25 h / -40 - 20 °C / Molecular sieve; Inert atmosphere

4.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; methanol / 4 h / 20 °C / Inert atmosphere

With pyridine; sodium hydride; pyridine hydrogenfluoride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In methanol; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1039/c3ob40958a