phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside

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Chemical Name:phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside
CAS No.:1448452-68-3
Molecular Formula:C₃₀H₃₈O₄SSi
Molecular Weight:522.781
Hs Code.:

Synonyms:phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside

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Technology Process of phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside

There total 1 articles about phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 913060-78-3
phenyl 3,5-O-(di-tert-butylsilanediyl)-1-thio-α-L-arabinofuranoside

: 939-26-4
2-bromomethylnaphthyl bromide

: 1448452-68-3
phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 3h; Inert atmosphere;
DOI:10.1039/c3ob40958a

Reference yield: 81.0%

: 1448452-68-3
phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside

: 1448452-72-9
phenyl 3,5-di-O-benzyl-2-O-(2-naphthyl)methyl-1-thio-α-Larabinofuranoside

Guidance literature:: With pyridine; pyridine hydrogenfluoride; In dichloromethane; at 0 ℃; for 2h; Inert atmosphere;
DOI:10.1039/c3ob40958a

Reference yield: 69.0%

: 1448452-88-7
3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

: 1448452-68-3
phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside

: 1448452-89-8
3-azidopropyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-2-O-naphthyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside

: C₆₅H₇₉N₃O₁₃Si

Guidance literature:: 3-azidopropyl 3,5-di-O-benzyl-β-L-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-β-L-arabinofuranoside; phenyl 3,5-O-(di-tert-butylsilanediyl)-2-O-2-naphthylmethyl-1-thio-α-L-arabinofuranoside; In dichloromethane; at 20 ℃; for 0.5h; Molecular sieve; Inert atmosphere;

With N-iodo-succinimide; silver trifluoromethanesulfonate; In dichloromethane; at -40 - 20 ℃; for 2.5h; Overall yield = 84 %; diastereoselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1039/c3ob40958a