[((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]⁽¹⁺⁾*BF₄^(1-)=[((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]BF₄

Base Information

• Chemical Name: [((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]⁽¹⁺⁾*BF₄^(1-)=[((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]BF₄
• CAS No.: 82582-67-0
• Molecular Formula: BF₄*C₄₂H₄₄IrO₂P₂
• Molecular Weight: 921.782
• Mol file: 82582-67-0.mol

Synonyms:[((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]⁽¹⁺⁾*BF₄^(1-)=[((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]BF₄

Chemical Property of [((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]⁽¹⁺⁾*BF₄^(1-)=[((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]⁽¹⁺⁾*BF₄^(1-)=[((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]BF₄

There total 9 articles about [((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]⁽¹⁺⁾*BF₄^(1-)=[((C₆H₅)3P)2IrH₂(CO(CH₃)2)2]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

[Ir(1,5-COD)(P(C6H5)3)2]BF4 (38834-40-1) → [((C6H5)3P)2IrH2(CO(CH3)2)2](1+)*BF4(1-)=[((C6H5)3P)2IrH2(CO(CH3)2)2]BF4 (82582-67-0)

Guidance literature:

With H₂; acetone; In acetone; under Ar, 0°C, H2 was bubbled into soln. for 45 min,; addn. of diethyl ether, filtered, washed with Et2O, dried in vac.;

Reference yield:

[Ir(1,5-COD)(P(C6H5)3)2]BF4 (38834-40-1) → [Ir(hydrido)2(acetone)2(triphenylphosphine)2](BF4) (82582-67-0,72414-17-6)

Guidance literature:

With hydrogen; acetone; In acetone; hydrogen bubbling at 0°C for 10 min.; addn. of Et2O ppt. the product, recrystn. from CH2Cl2/Et2O, elem. anal.;

DOI:10.1021/ja00365a021

Reference yield:

2-(diethylamino)pyridine (36075-06-6) + [(2)H2Ir(acetone)2(triphenylphosphine)2](BF4) → [Ir(hydrido)2(acetone)2(triphenylphosphine)2](BF4) (82582-67-0,72414-17-6) + cis,trans-[Ir(hydrido)2(triphenylphosphine)2(2-pyridyl-N(C(2)H2CH3)C(CH3))](BF4)

Guidance literature:

In dichloromethane; (N2 or Ar); using Schlenk techniques; dissolving of py-NEt2 and (Ir(2)H2(acetone)2(PPh3)2)(BF4) in CH2Cl2 in NMR tube for 15 min at room temp.; removal of volatiles in vac.; monitoring by NMR;

DOI:10.1021/ja048473j

upstream raw materials:

[Ir(1,5-COD)(P(C₆H₅)3)2]BF₄

hydrogen

acetone

2-(diethylamino)pyridine

Downstream raw materials:

Ir(C₇H₉)H{(C₆H₅)3P}2⁽¹⁺⁾*BF₄^(1-)

dihydrido(η3(Cl,C,C)-2,6-dichlorostyrene)bis(triphenylphosphine)iridium(III) tetrafluoroborate