MoBr₃(C₆H₅P(CH₂CH₂P(C₆H₅)2)2)

Base Information

• Chemical Name: MoBr₃(C₆H₅P(CH₂CH₂P(C₆H₅)2)2)
• CAS No.: 74707-27-0
• Molecular Formula: C₃₄H₃₃Br₃MoP₃
• Molecular Weight: 870.209
• Mol file: 74707-27-0.mol

Synonyms:MoBr₃(C₆H₅P(CH₂CH₂P(C₆H₅)2)2)

Chemical Property of MoBr₃(C₆H₅P(CH₂CH₂P(C₆H₅)2)2)

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of MoBr₃(C₆H₅P(CH₂CH₂P(C₆H₅)2)2)

There total 7 articles about MoBr₃(C₆H₅P(CH₂CH₂P(C₆H₅)2)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Mo(N2)2(C6H5P(C2H4P(C6H5)2)2)P(C6H5)3*0.5C4H8O → MoBr3(C6H5P(CH2CH2P(C6H5)2)2) (74707-27-0)

Guidance literature:

With hydrogen bromide; In tetrahydrofuran; byproducts: NH4Br, N2, P(C6H5)3; THF and HBr condensed into Mo-complex cooled to -196°C; warmed to room temp. and stirred for 24-36 h; pptd.; evapd.; washed with ethanol; dried; elem. anal.;

DOI:10.1021/ja00539a035

Reference yield: 8.0%

trans-[Mo(N2)(PhP(CH2CH2PPh2)2)(PPh3)] (74707-26-9,75420-24-5) → MoBr3(C6H5P(CH2CH2P(C6H5)2)2) (74707-27-0) + nitrogen (7727-37-9) + ammonia (7664-41-7)

Guidance literature:

With hydrogen bromide; In methanol; complex was treated with anhydrous HCl in THF;

DOI:10.1016/S0020-1693(00)90337-2

Reference yield:

trans-[Mo(N2)(PhP(CH2CH2PPh2)2)(PPh3)] (74707-26-9,75420-24-5) → MoBr3(C6H5P(C2H4P(C6H5)2)2) (74707-27-0) + hydrazine (302-01-2,78206-91-4,119775-10-9,75013-58-0)

Guidance literature:

With hydrogen bromide; In tetrahydrofuran; byproducts: NH4Br, PPh3, N2; liquid HBr added to Mo complex in absence of solvent, added THF, stirred; Kinetics;

DOI:10.1021/ja00358a036

upstream raw materials:

trans-[Mo(N₂)(PhP(CH₂CH₂PPh₂)2)(PPh₃)]

triphenylphosphine hydrobromide

hydrogen bromide