3-((2S,3S,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester

Base Information

Chemical Name:3-((2S,3S,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester
CAS No.:240415-56-9
Molecular Formula:C₃₂H₃₇N₃O₆
Molecular Weight:559.662
Hs Code.:

Synonyms:3-((2S,3S,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester

Suppliers and Price of 3-((2S,3S,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-((2S,3S,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-((2S,3S,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester

There total 2 articles about 3-((2S,3S,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 240415-68-3
3-((4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-2-methyl-propionic acid methyl ester

: 240415-56-9
3-((2S,3S,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester

Guidance literature:: 3-((4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-2-methyl-propionic acid methyl ester; With sodium azide; ammonium cerium(IV) nitrate; In acetonitrile; at -20 ℃;

With triethylsilane; boron trifluoride diethyl etherate; In acetonitrile;
DOI:10.1016/S0040-4039(99)01055-2

Reference yield:

: 3-((4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-2-methyl-propionic acid

: 240415-56-9
3-((2S,3S,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-2-methyl-propionic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: diethyl ether

2.1: ceric ammonium nitrate; sodium azide / acetonitrile / -20 °C

2.2: 30 percent / Et₃SiH; BF₃*Et₂O / acetonitrile

With sodium azide; ammonium cerium(IV) nitrate; In diethyl ether; acetonitrile; 1.1: Esterification / 2.1: Reduction / 2.2: Reduction;
DOI:10.1016/S0040-4039(99)01055-2