7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine)

Base Information

• Chemical Name: 7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine)
• CAS No.: 952188-97-5
• Molecular Formula: C₂₃H₂₉NO
• Molecular Weight: 335.489
• Mol file: 952188-97-5.mol

Synonyms:7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine)

Chemical Property of 7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine)

There total 1 articles about 7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

2,3-dihydro-7-hydroxy-3,4-dimethyl-1H-indan-1-one (53005-72-4) + 2,6-diisopropylbenzenamine (24544-04-5) → 7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine) (952188-97-5)

Guidance literature:

2,6-diisopropylbenzenamine; With titanium tetrachloride; In toluene; at 20 - 90 ℃; for 1h;

2,3-dihydro-7-hydroxy-3,4-dimethyl-1H-indan-1-one; In toluene; at 90 ℃; for 48h; Further stages.;

DOI:10.1039/b708048d

Reference yield: 45.0%

7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine) (952188-97-5) + trichlorotris(tetrahydrofuran)chromium(III) (10170-68-0,16997-54-9) + lithiumpentamethylcyclopentadiene → [(η5-pentamethylcyclopentadienyl)Cr(C6H3-2,6-(i-Pr)2-NCC2H3(CH3)C6H2(CH3)O)Cl] (1172617-50-3)

Guidance literature:

With sodium hydride; In tetrahydrofuran; under Ar; NaH added to stirred soln. of ligand in THF at 0°C; warmed to room temp.; stirred (12 h); filtrate added at -78°C to soln. of Cr complex prepared from CrCl3(THF)3 and (C5Me5)Li in THF; warmed to room temp.; stirred overnight; solvent removed under vac.; dissolved in CH2Cl2; filtered; filtrate concd.; mixed with hexane; crystd. at -30°C; elem. anal.;

DOI:10.1021/om900279p

Reference yield:

7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine) (952188-97-5) + bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) → [((CH3)5C5)IrCl(O(CH3)2C9H5NC6H3(C3H7)2)] (1051494-87-1)

Guidance literature:

With n-BuLi; In tetrahydrofuran; hexane; byproducts: LiCl; hexane soln. of n-BuLi (0.45 mmol) added dropwise to THF soln. of ligand(0.41 mmol) at -78°C, warmed slowly to room temp., stirred for 3 h, channaled to suspn. of Ir compd. (0.2 mmol) in THF, stirred overnigh t; evapd., extd. (toluene), filtered to remove LiCl, concd., crystd. (-30°C), recrystd. (hexane/toluene, -30°C);

DOI:10.1039/b803382j

upstream raw materials:

2,3-dihydro-7-hydroxy-3,4-dimethyl-1H-indan-1-one

2,6-diisopropylbenzenamine

Downstream raw materials:

[Cu(7-hydroxy-3,4-dimethylindan-1-(N-2,6-diisopropylphenylimine)(-1H))2]

[((CH₃)5C₅)IrCl(O(CH₃)2C₉H₅NC₆H₃(C₃H₇)2)]

[(η5-pentamethylcyclopentadienyl)Cr(C6H3-2,6-(i-Pr)2-NCC2H3(CH3)C6H2(CH3)O)Cl]