Technology Process of dl-cyclopenol O-acetate
There total 8 articles about dl-cyclopenol O-acetate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
for 648h;
Ambient temperature;
DOI:10.1021/jo00133a042
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 1.) sodium hydride / 1.) THF, 0 deg C, 1.5 h, 2a.) 0 deg C, 30 min, 2b.) room temp., 3 h
2: 93 percent / aq. potassium carbonate / methanol / 3 h / Ambient temperature
3: 41 percent / triphenyl phosphine, tri-n-butylamine / palladium acetate / hexamethylphosphoric acid triamide / 48 h / 120 °C / 3800 Torr
4: 84.6 percent / 10percent aq. hydrochloric acid / methanol / 3 h / 50 °C
5: 10 percent / sodium acetate / 3 h / 150 °C
6: 24 percent / MCPBA / CH2Cl2 / 648 h / Ambient temperature
With
hydrogenchloride; tributyl-amine; sodium acetate; sodium hydride; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine;
palladium diacetate;
In
methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
DOI:10.1021/jo00133a042
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 93 percent / aq. potassium carbonate / methanol / 3 h / Ambient temperature
2: 41 percent / triphenyl phosphine, tri-n-butylamine / palladium acetate / hexamethylphosphoric acid triamide / 48 h / 120 °C / 3800 Torr
3: 84.6 percent / 10percent aq. hydrochloric acid / methanol / 3 h / 50 °C
4: 10 percent / sodium acetate / 3 h / 150 °C
5: 24 percent / MCPBA / CH2Cl2 / 648 h / Ambient temperature
With
hydrogenchloride; tributyl-amine; sodium acetate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine;
palladium diacetate;
In
methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
DOI:10.1021/jo00133a042
