4-bromo-3-[2,5-dihydro-4-(phenylthio)methyl-1-tosylpyrrol-2-yl]methyl-1-tosylindole

Base Information

Chemical Name:4-bromo-3-[2,5-dihydro-4-(phenylthio)methyl-1-tosylpyrrol-2-yl]methyl-1-tosylindole
CAS No.:1496532-96-7
Molecular Formula:C₃₄H₃₁BrN₂O₄S₃
Molecular Weight:707.733
Hs Code.:

Synonyms:4-bromo-3-[2,5-dihydro-4-(phenylthio)methyl-1-tosylpyrrol-2-yl]methyl-1-tosylindole

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Chemical Property of 4-bromo-3-[2,5-dihydro-4-(phenylthio)methyl-1-tosylpyrrol-2-yl]methyl-1-tosylindole

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Technology Process of 4-bromo-3-[2,5-dihydro-4-(phenylthio)methyl-1-tosylpyrrol-2-yl]methyl-1-tosylindole

There total 3 articles about 4-bromo-3-[2,5-dihydro-4-(phenylthio)methyl-1-tosylpyrrol-2-yl]methyl-1-tosylindole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₈H₂₇BrN₂O₅S₂

: 882-33-7
diphenyldisulfane

: 1496532-96-7
4-bromo-3-[2,5-dihydro-4-(phenylthio)methyl-1-tosylpyrrol-2-yl]methyl-1-tosylindole

Guidance literature:: With tributylphosphine; In benzene; at 20 ℃; for 0.5h;
DOI:10.1021/jo4023588

Reference yield:

: 913484-72-7
N-(2-hydroxy-but-3-ynyl)-4-methylbenzenesulfonamide

: 1496532-96-7
4-bromo-3-[2,5-dihydro-4-(phenylthio)methyl-1-tosylpyrrol-2-yl]methyl-1-tosylindole

Guidance literature:: Multi-step reaction with 3 steps

1: iron(III) chloride / dichloromethane / 0.2 h / 20 - 45 °C

2: cerium(III) chloride heptahydrate; sodium tetrahydroborate / tetrahydrofuran; methanol / 0.5 h / 0 °C

3: tributylphosphine / benzene / 0.5 h / 20 °C

With iron(III) chloride; sodium tetrahydroborate; tributylphosphine; cerium(III) chloride heptahydrate; In tetrahydrofuran; methanol; dichloromethane; benzene; 1: |Aza-Cope Rearrangement / 2: |Luche Cerium Reduction;
DOI:10.1021/jo4023588

Reference yield:

: 1273005-83-6
2-(4-bromo-1-tosyl-1H-indol-3-yl)acetaldehyde

: 1496532-96-7
4-bromo-3-[2,5-dihydro-4-(phenylthio)methyl-1-tosylpyrrol-2-yl]methyl-1-tosylindole

Guidance literature:: Multi-step reaction with 3 steps

1: iron(III) chloride / dichloromethane / 0.2 h / 20 - 45 °C

2: cerium(III) chloride heptahydrate; sodium tetrahydroborate / tetrahydrofuran; methanol / 0.5 h / 0 °C

3: tributylphosphine / benzene / 0.5 h / 20 °C

With iron(III) chloride; sodium tetrahydroborate; tributylphosphine; cerium(III) chloride heptahydrate; In tetrahydrofuran; methanol; dichloromethane; benzene; 1: |Aza-Cope Rearrangement / 2: |Luche Cerium Reduction;
DOI:10.1021/jo4023588