trans-1,2-Dimethyl-1,2-dinitrocyclohexane

Base Information

• Chemical Name: trans-1,2-Dimethyl-1,2-dinitrocyclohexane
• CAS No.: 116725-27-0
• Molecular Formula: C₈H₁₄N₂O₄
• Molecular Weight: 202.21
• Mol file: 116725-27-0.mol

Synonyms:trans-1,2-Dimethyl-1,2-dinitrocyclohexane

Chemical Property of trans-1,2-Dimethyl-1,2-dinitrocyclohexane

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of trans-1,2-Dimethyl-1,2-dinitrocyclohexane

There total 1 articles about trans-1,2-Dimethyl-1,2-dinitrocyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

1,2-dimethylcyclohexene (1674-10-8) → trans-1,2-Dimethyl-1,2-dinitrocyclohexane (116725-27-0)

Guidance literature:

With dinitrogen tetraoxide; In diethyl ether; at 0 ℃; for 6h;

DOI:10.1016/S0040-4039(00)74310-3

Reference yield:

trans-1,2-Dimethyl-1,2-dinitrocyclohexane (116725-27-0) → trans-N,N’-dimethylcyclohexane-1,2-diamine (134150-25-7,134234-69-8,134234-70-1)

Guidance literature:

With hydrogen; palladium hydroxide - carbon; In acetic acid; under 2280 Torr;

DOI:10.1016/S0040-4039(00)74310-3

Reference yield:

trans-1,2-Dimethyl-1,2-dinitrocyclohexane (116725-27-0) → (1R,2R)-1,2-Dimethyl-1,2-cyclohexanediammonium bis (S)-mandelate (134308-25-1,134308-26-2)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂ / Pd(OH)2-C / acetic acid / 2280 Torr

2: ethanol / 0.5 h / Heating

With hydrogen; palladium hydroxide - carbon; In ethanol; acetic acid;

DOI:10.1016/S0040-4039(00)74310-3

upstream raw materials:

1,2-dimethylcyclohexene

Downstream raw materials:

trans-N,N’-dimethylcyclohexane-1,2-diamine

(1R,2R)-1,2-Dimethyl-1,2-cyclohexanediammonium bis (S)-mandelate