[Pd(C₆H₅N(H)N=CMe(C₅H₄N))(Cl₂)]

Base Information

• Chemical Name: [Pd(C₆H₅N(H)N=CMe(C₅H₄N))(Cl₂)]
• CAS No.: 155804-82-3
• Molecular Formula: C₁₃H₁₃Cl₂N₃Pd
• Molecular Weight: 388.592
• Mol file: 155804-82-3.mol

Synonyms:[Pd(C₆H₅N(H)N=CMe(C₅H₄N))(Cl₂)]

Chemical Property of [Pd(C₆H₅N(H)N=CMe(C₅H₄N))(Cl₂)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(C₆H₅N(H)N=CMe(C₅H₄N))(Cl₂)]

There total 2 articles about [Pd(C₆H₅N(H)N=CMe(C₅H₄N))(Cl₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

lithium tetrachloropalladate + 2-acetylpyridine phenylhydrazone (7734-05-6) → [Pd(C6H5N(H)N=CMe(C5H4N))(Cl2)] (155804-82-3)

Guidance literature:

With NaAcO; In methanol; a stirred soln. of Pd-contg. compd. (0.76 mmol) in methanol was treated with a ligand (0.76 mmol) and sodium acetate (0.76 mmol); the mixt. was stirred at room temp. for 24 h; the ppt. was filtered off and dried in air; elem. anal.;

DOI:10.1016/j.jorganchem.2005.04.039

Reference yield: 86.0%

lithium chloride + palladium dichloride + 2-acetylpyridine phenylhydrazone (7734-05-6) → [Pd(C6H5N(H)N=CMe(C5H4N))(Cl2)] (155804-82-3)

Guidance literature:

In methanol; PdCl2 is suspended in MeOH and LiCl4 is added, after stirring for 0,5 hat 60°C the soln. is filtd. and the ligand dissolved in MeOH, HCl is added, mixt. is stirred for 24 h; solid is collected by filtn., washed with MeOH and Et2O and dried in vac., elem. anal.;

Reference yield:

[Pd(C6H5N(H)N=CMe(C5H4N))(Cl2)] (155804-82-3) → [[Pd(C5NH4C(CH3)NNHC6H4)]2((C6H5)2P)2CH2](2+)*2BF4(1-)=[[Pd(C5H4NC(CH3)NNHC6H4)]2((C6H5)2P)2CH2](BF4)2

Guidance literature:

Multi-step reaction with 2 steps

1: acetone

2: acetone

In acetone;

upstream raw materials:

2-acetylpyridine phenylhydrazone

Downstream raw materials:

[Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]⁽¹⁺⁾*BF₄^(1-)=[Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]BF₄

[Pd(P(OC₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]⁽¹⁺⁾*BF₄^(1-)=[Pd(P(OC₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]BF₄

[Pd(C₆H₄N(H)N=CMe(C₅H₄N))(PPh₃)][F₃CSO₃]

Refernces

• 1、 García-Herbosa, Gabriel,Mu?oz, Asunción,Miguel, Daniel,García-Granda, Santiago. "Cyclopalladated complexes of 2-acetylpyridine phenylhydrazone: A terdentate C,N,N′ donor ligand". . p. 1775 - 1780. Retrieved 2008/10/08.