2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane

Base Information

Chemical Name:2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane
CAS No.:131691-36-6
Molecular Formula:C₂₁H₄₄OSi₂
Molecular Weight:368.751
Hs Code.:

Synonyms:2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane

Suppliers and Price of 2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane

There total 7 articles about 2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 5180-93-8
(methoxydimethylsilyl)(trimethylsilyl)methane

: 131691-34-4
2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethylcyclohexanone

: 131691-36-6
2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane

Guidance literature:: With tert.-butyl lithium; In pentane; Ambient temperature;
DOI:10.1016/S0040-4020(01)80810-3

Reference yield: 31.0%

: 120086-03-5
<(methoxydimethylsilyl)(trimethylsilyl)methyl>lithium

: 131691-34-4
2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethylcyclohexanone

: 131691-36-6
2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane

Guidance literature:: In pentane;
DOI:10.1039/c39900001487

Reference yield:

: 131691-33-3
(2S,5R)-2-[((R)-2'-tert-butyldimethylsilyloxy)-1'-methylethyl]-5-methylcyclohexan-1-one

: 131691-36-6
2S-(1'-t-butyldimethylsilyloxy-2'R-propyl)-5R,6S-dimethyl-1-E/Z-trimethylsilylmethylenecyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1: 58 percent / lithium diisopropylamide / tetrahydrofuran; hexane / 0.42 h / Ambient temperature

2: 41 percent / t-butyllithium / pentane / Ambient temperature

With tert.-butyl lithium; lithium diisopropyl amide; In tetrahydrofuran; hexane; pentane;
DOI:10.1016/S0040-4020(01)80810-3