methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside

Base Information

• Chemical Name: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside
• CAS No.: 50692-55-2
• Molecular Formula: C₁₃H₁₉IO₈
• Molecular Weight: 430.194
• Mol file: 50692-55-2.mol

Synonyms:methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside

Chemical Property of methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside

There total 1 articles about methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ Acetic acid 3,5-diacetoxy-2-iodomethyl-6-methoxy-tetrahydro-pyran-4-yl ester (6304-96-7,7511-38-8,35904-61-1,35904-63-3,50692-55-2,56570-97-9,56570-98-0,56570-99-1,98523-69-4)

Guidance literature:

Aus Methyl-α-D-Mannopyranosid (1), p-TsCl, NaI;

Reference yield: 80.0%

methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside (50692-55-2) + (2-phenyl)-selenoacetic acid (844697-83-2) → C21H26O9Se (1040413-37-3)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; toluene; at 20 ℃; for 2h;

DOI:10.1021/ja8034448

Reference yield: 50.0%

methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside (50692-55-2) + ethyl acetate (141-78-6) → methyl-2,3,4-tri-O-acetyl-6-deoxy-α-D-luxo-hex-5-enopyranoside (155049-45-9) + methyl 2,3,4,6-tetra-O-acetyl-α-D-mannopyranoside (604-70-6,4860-85-9,5019-22-7,5019-23-8,5019-24-9,5019-25-0,14795-19-8,17460-42-3,19189-52-7,25217-94-1,30657-67-1,34254-54-1,39598-81-7,39598-82-8,39598-85-1,39598-86-2,39598-90-8,39598-92-0,41398-87-2,51819-80-8,51819-84-2,51819-85-3,51819-86-4,51897-78-0,73136-69-3,75880-73-8,92619-79-9,92934-57-1,92934-58-2,114298-54-3,128657-15-8,132562-65-3,141042-95-7)

Guidance literature:

methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside; With 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; at 110 ℃;

ethyl acetate; Further stages.;

DOI:10.1021/jo016378c

Downstream raw materials:

methyl-2,3,4-tri-O-acetyl-6-deoxy-α-D-luxo-hex-5-enopyranoside

methyl 2,3,4,6-tetra-O-acetyl-α-D-mannopyranoside

methyl 2,3,4-tri-O-benzyl-5-methylene-α-D-lyxopyranoside

C₂₁H₂₆O₉Se