[PtCl(PBu₃)2(naphthalene diimide)]

Base Information

Chemical Name:[PtCl(PBu₃)2(naphthalene diimide)]
CAS No.:1173397-64-2
Molecular Formula:C₅₄H₇₉ClN₂O₄P₂Pt
Molecular Weight:1112.71
Hs Code.:

[PtCl(PBu<sub>3</sub>)2(naphthalene diimide)]

Synonyms:[PtCl(PBu₃)2(naphthalene diimide)]

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Chemical Property of [PtCl(PBu₃)2(naphthalene diimide)]

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Technology Process of [PtCl(PBu₃)2(naphthalene diimide)]

There total 1 articles about [PtCl(PBu₃)2(naphthalene diimide)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 926643-77-8
N-(4’-ethynylphenyl)-N’-(octyl)naphthalene-1,8:4,5-tetracarboxydiimide

: 15390-92-8,15391-01-2,15076-72-9
cis-dichlorobis(tri-n-butylphosphine)platinum(II)

: 1173397-64-2
[PtCl(PBu₃)2(naphthalene diimide)]

Guidance literature:: With diisopropylamine; In further solvent(s); two Pt complexes in i-Pr2NH-MeCN refluxed for 12 h; according to K. Sonogashira et al., J. Organomet. Chem., 1978, 145, 101 and N. Hagihara et al., Adv. Polym. Sci., 1980, 40, 149;
DOI:10.1021/om900195p

Reference yield: 50.1%

: 1173397-64-2
[PtCl(PBu₃)2(naphthalene diimide)]

: 1173397-67-5
HCCC₆H₄((C₂)Pt(P(C₄H₉)3)2(C₂C₆H₄))4CCH

: C₈H₁₇NC₁₄H₄O₄NC₆H₄(CCPt(PBu₃)2CC(1,4-phenylene))6C₁₄H₄O₄NC₈H₁₇

Guidance literature:: With diethylamine; copper(l) iodide; In tetrahydrofuran; under Ar; soln. of two Pt complexes and Et2NH in THF degassed with Ar for 5 min; CuI added; stirred at room temp. for 3 h; quenched with deionized H2O; diluted with CH2Cl2; washed with brine; org. layer dried (Na2SO4); solvent removed; purified by flash chromy. (silica gel, CHCl3-hexane 2:1); red band collected; solvent removed; elem. anal.;
DOI:10.1021/om900195p

Reference yield: 45.0%

: 2HCCC₆H₄C₂^(1-)*8Pt⁽²⁺⁾*16P(C₄H₉)3*7C₂C₆H₄C₂^(2-)=HCCC₆H₄((C₂)Pt(P(C₄H₉)3)2(C₂C₆H₄))8CCH

: 1173397-64-2
[PtCl(PBu₃)2(naphthalene diimide)]

: C₈H₁₇NC₁₄H₄O₄NC₆H₄(CCPt(PBu₃)2CC(1,4-phenylene))10NC₁₄H₄O₄NC₈H₁₇

Guidance literature:: With diethylamine; copper(l) iodide; In tetrahydrofuran; under Ar; soln. of two Pt complexes and Et2NH in THF degassed with Ar for 10 min; CuI added; stirred at room temp. for 4 h; diluted with CH2Cl2; washed with deionized H2O and brine; org. layer dried (Na2SO4); solvent evapd.; purified by flash chromy. (silica gel, CH2Cl2-hexane-MeOH 2:1:(1%) to 5:1:(1%)); third fraction collected; solvent evapd.; elem. anal.;
DOI:10.1021/om900195p