Dichloroplatinum;tributylphosphanium

Base Information

• Chemical Name: Dichloroplatinum;tributylphosphanium
• CAS No.: 15390-92-8
• Molecular Formula: C₂₄H₅₄Cl₂P₂Pt
• Molecular Weight: 670.626
• NSC Number: 162925,162924
• Mol file: 15390-92-8.mol

Synonyms:NSC162924;15390-92-8;15391-01-2;SCHEMBL1460473;NSC162925;NSC-162924;NSC-162925

Chemical Property of Dichloroplatinum;tributylphosphanium

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 18
• Exact Mass: 671.288225
• Heavy Atom Count: 29
• Complexity: 197

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[PH+](CCCC)CCCC.CCCC[PH+](CCCC)CCCC.Cl[Pt]Cl

Technology Process of Dichloroplatinum;tributylphosphanium

There total 7 articles about Dichloroplatinum;tributylphosphanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

[1,4-tetramethyleneplatinum(II)(P(n-Bu)3)2] (61160-68-7) → 1-butylene (106-98-9,9003-28-5) + cis-dichlorobis(tri-n-butylphosphine)platinum(II) (15390-92-8,15391-01-2,15076-72-9) + cis-[Pt(P(n-Bu3))2(CH2Cl)Cl] (68092-91-1) + trans-[Pt(P(n-Bu3))2(CH2Cl)Cl] (68092-91-1) + cyclobutane (287-23-0)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); under N2, photolysis of CH2Cl2 soln. of Pt complex at 313 nm for 1-3 h; not isolated, detected by NMR;

DOI:10.1016/0022-328X(83)80124-7

Reference yield: 45.0%

tributylphosphine (998-40-3) + 4-methoxyphenylacetylen (768-60-5) + platinum(II) chloride (10025-65-7) → trans-dichloro-bis(tri-n-butylphosphine)platinum(II) (15391-01-2,15076-72-9,15390-92-8) + trans-chloro-[4-methoxyphenylethynyl]bis(tri-n-butylphosphine)platinum(II) (915318-05-7)

Guidance literature:

With triethylamine; In tetrahydrofuran; triethylamine; at 160°C for 1 h;

DOI:10.1021/om060616i

Reference yield:

Pt(P(C4H9)3)2(H2NC2H4NH2)(2+)*PtCl4(2-)=[Pt(P(C4H9)3)2(H2NC2H4NH2)][PtCl4] (77070-37-2,144082-35-9,144082-32-6) → dichloro(ethylenediamine)platinum(II) (14096-51-6) + cis-dichlorobis(tri-n-butylphosphine)platinum(II) (15390-92-8,15391-01-2,15076-72-9)

Guidance literature:

In neat (no solvent); heating at 153-167°C; monitoring by differential thermal anal.;

upstream raw materials:

sym-trans-{Pt₂Cl₄(P(C₄H₉)3)2}

Dimethyl(phenyl)phosphine

[(P((CH₂)3CH₃)3)ClPdCl₂PtCl(P((CH₂)3CH₃)3)]

tributylphosphine