(2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II)

Base Information

• Chemical Name: (2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II)
• CAS No.: 1058186-88-1
• Molecular Formula: C₅₀H₃₃N₅Ni
• Molecular Weight: 762.536
• Mol file: 1058186-88-1.mol

Synonyms:(2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II)

Chemical Property of (2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II)

There total 5 articles about (2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

ethyl 6-bromo-1-ethyl-4-oxo-1,4-dihydroquinoline-3-carboxylate (179942-70-2) + (2-amino-5,10,15,20-tetraphenylporphyrinato)-nickel(II) (189192-29-8) + 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl (76144-87-1,76189-55-4,76189-56-5,136655-44-2,98327-87-8) → (2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II) (1058186-88-1) + 2-(3-Ethoxycarbonyl-1-ethyl-4-oxo-1,4-dihydroquinolin-6-ylamino)-5,10,15,20-tetraphenylporphyrinatonickel(II)

Guidance literature:

With potassium tert-butylate; palladium diacetate; In toluene; at 110 ℃; Inert atmosphere;

DOI:10.1039/c5ra11070j

Reference yield: 69.0%

bromobenzene (108-86-1,52753-63-6) + (2-amino-5,10,15,20-tetraphenylporphyrinato)-nickel(II) (189192-29-8) → (2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II) (1058186-88-1)

Guidance literature:

With potassium tert-butylate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In toluene; at 100 ℃; for 24h; Inert atmosphere;

DOI:10.1021/jo800975c

Reference yield: 67.0%

(2-amino-5,10,15,20-tetraphenylporphyrinato)-nickel(II) (189192-29-8) + ethyl 6-bromo-4-oxo-1-pentyl-1,4-dihydroquinoline-3-carboxylate (1374769-82-0) + 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl (76144-87-1,76189-55-4,76189-56-5,136655-44-2,98327-87-8) → (2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II) (1058186-88-1) + 2-(3-Ethoxycarbonyl-4-oxo-1-pentyl-1,4-dihydroquinolin-6-ylamino)-5,10,15,20-tetraphenylporphyrinatonickel(II)

Guidance literature:

With potassium tert-butylate; palladium diacetate; In toluene; at 110 ℃; Inert atmosphere;

DOI:10.1039/c5ra11070j

upstream raw materials:

bromobenzene

(2-amino-5,10,15,20-tetraphenylporphyrinato)-nickel(II)

nickel(II) 2-nitro-5,10,15,20-tetraphenylporphyrinate

5-iodo-1,3,3-trimethylindolin-2-one

Downstream raw materials:

C₅₀H₃₁N₅Ni

C₅₀H₃₁CuN₅

C₅₀H₃₁N₅Pd