6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione

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Chemical Name:6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione
CAS No.:73168-13-5
Molecular Formula:C₃₂H₂₆O₁₁
Molecular Weight:586.552
Hs Code.:

6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione

Synonyms:6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione

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Chemical Property of 6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione

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Technology Process of 6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione

There total 5 articles about 6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 73168-12-4
1-methyl-6-(phenylmethoxy)-10-<(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxy>benzo<1>benzopyrano<5,4,3-cde><1>benzopyran-5,12-dione

: 73168-13-5
6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione

Guidance literature:: With sodium methylate; In methanol; chloroform; at 0 ℃; for 1.33333h;
DOI:10.1021/jm00179a015

Reference yield:

: 100-39-0
benzyl bromide

: 73168-13-5
6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Ag₂O, 2.) ag. HCl / 1.) CH₃CN, 80 deg C, 2 h, 2.) reflux

2: 54 percent / silver carbonate, pyridine / 2 h / Ambient temperature

3: 71 percent / sodium methoxide / CHCl₃; methanol / 1.33 h / 0 °C

With pyridine; hydrogenchloride; sodium methylate; silver carbonate; silver(l) oxide; In methanol; chloroform;
DOI:10.1021/jm00179a015

Reference yield:

: 73168-10-2
10-hydroxy-1-methyl-6-(phenylmethoxy)benzo<1>benzopyrano<5,4,3-cde><1>benzopyran-5,12-dione

: 73168-13-5
6-Benzyloxy-1-methyl-10-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-benzo[h]chromeno[5,4,3-cde]chromene-5,12-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 54 percent / silver carbonate, pyridine / 2 h / Ambient temperature

2: 71 percent / sodium methoxide / CHCl₃; methanol / 1.33 h / 0 °C

With pyridine; sodium methylate; silver carbonate; In methanol; chloroform;
DOI:10.1021/jm00179a015