methyl-2-chlorophenylketene

Base Information

• Chemical Name: methyl-2-chlorophenylketene
• CAS No.: 1255944-65-0
• Molecular Formula: C₉H₇ClO
• Molecular Weight: 166.607
• Mol file: 1255944-65-0.mol

Synonyms:methyl-2-chlorophenylketene

Chemical Property of methyl-2-chlorophenylketene

Chemical Property:

Purity/Quality:

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Technology Process of methyl-2-chlorophenylketene

There total 1 articles about methyl-2-chlorophenylketene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C9H7ClN2O → methyl-2-chlorophenylketene (1255944-65-0)

Guidance literature:

In 1,2-dichloro-ethane; at 20 ℃; for 4h; Inert atmosphere; Schlenk technique; Irradiation;

DOI:10.1039/c8cc10157d

Reference yield: 99.0%

methyl-2-chlorophenylketene (1255944-65-0) → Z-3-(2-chlorophenyl)-4-(1-(2-chlorophenyl)ethylidene)-3-methyloxetan-2-one

Guidance literature:

With tributylphosphine; In dichloromethane; at 0 ℃; for 1.5h; Inert atmosphere;

DOI:10.1016/j.tet.2020.131838

Reference yield: 90.0%

2,4-dimethyl-1H-pyrrole (625-82-1) + methyl-2-chlorophenylketene (1255944-65-0) → C15H16ClNO

Guidance literature:

With C₄₅H₃₁O₄P; In 1,2-dichloro-ethane; at 20 ℃; for 30h; enantioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1039/d1cc05307h

Downstream raw materials:

Z-3-(2-chlorophenyl)-4-(1-(2-chlorophenyl)ethylidene)-3-methyloxetan-2-one