(η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)

Base Information

• Chemical Name: (η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)
• CAS No.: 86543-64-8
• Molecular Formula: C₁₉H₁₅CoS₂
• Molecular Weight: 366.453
• Mol file: 86543-64-8.mol

Synonyms:(η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)

Chemical Property of (η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)

There total 18 articles about (η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

sulfur (10544-50-0) + bis(μ3-η1-benzylidyne)tris(η5-cyclopentadienylcobalt) → (η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III) (86543-64-8) + 2Co(2+)*Co(3+)*3C5H5(1-)*2S(2-)=((C5H5)Co)3S2

Guidance literature:

In chloroform; complex was reacted with excess S8, CHCl3, 48 h, heating;

DOI:10.1021/ja00354a070

Reference yield: 99.0%

sulfur (10544-50-0) + bis(μ3-η1-benzylidyne)tris(η5-cyclopentadienylcobalt) → (η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III) (86543-64-8) + {CoCp}3(S)2

Guidance literature:

In chloroform; N2 bubbled through soln. of S in CHCl3 for several hours, Co-compd. added and mixt. boiled for 2d, alumina added and solvent removed; chromy. (alumina, hexane, hexane-ether), elem. anal.;

DOI:10.1016/S0277-5387(00)86322-6

Reference yield: 55.0%

(η5-cyclopentadienyl)-η4-cycloocta-1,5-dienecobalt(I) (12184-35-9) + 2,5-diphenyl-1,3-dithiolylium-4-olate (20850-89-9) → (η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III) (86543-64-8)

Guidance literature:

In benzene; Irradiation (UV/VIS); under Ar, irrdn. with a medium pressure mercury lamp at room temp. for 20 h;

upstream raw materials:

sulfur

dicarbonylcyclopentadienylcobalt

2,5-diphenyl-1,3-dithiolylium-4-olate

(η5-cyclopentadienyl)-η4-cycloocta-1,5-dienecobalt(I)

Downstream raw materials:

dimethyl 4,5-diphenylthiophene-2,3-dicarboxylate

(η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III)

diphenyl acetylene

[(cyclopentadienyl)Co((NH)S(C₆H₂FNO₂))]