(η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III)

Base Information

• Chemical Name: (η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III)
• CAS No.: 86543-67-1
• Molecular Formula: C₁₁H₁₁CoO₄S₂
• Molecular Weight: 330.331
• Mol file: 86543-67-1.mol

Synonyms:(η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III)

Chemical Property of (η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III)

There total 17 articles about (η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(η5-cyclopentadienyl)(p-toluenesulfonylimido-kN-thio-kS-ethene-2-thiolato-kS)cobalt(III) → 4-toluenesulfonyl azide (941-55-9) + (η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III) (86543-67-1)

Guidance literature:

In neat (no solvent); 177-178°C;

DOI:10.1016/S0022-328X(00)00408-3

Reference yield: 75.0%

C5H5Co(SC(C6H5)NSC(COOCH3)C(COOCH3)) → (η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III) (86543-67-1) + (η(5)-cyclopentadienyl)(1-phenylmethanimine-N,1-dithiolato)cobalt(III)

Guidance literature:

In benzene; byproducts: benzonitrile, dimethyl acetylenedicarboxylate; thermolysis of the Co-compd. in benzene under reflux for 2 h;

DOI:10.1246/cl.1994.473

Reference yield: 70.0%

(η(5)-cyclopentadienyl)(1-phenylmethanimine-N,1-dithiolato)cobalt(III) + dimethyl acetylenedicarboxylate (762-42-5) → (η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III) (86543-67-1) + C5H5Co(SC(C6H5)NSC(COOCH3)C(COOCH3))

Guidance literature:

In not given; Co-complex reacts with dimethyl acetylenedicarboxylate at room temp. for 24 h; elem. anal.;

DOI:10.1246/cl.1994.473

upstream raw materials:

(η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)

dimethyl acetylenedicarboxylate

triphenylphosphine

triphenyl phosphite

Downstream raw materials:

[(cyclopentadienyl)Co((NH)S(C₆H₂FNO₂))]