phenyl 10,11-dimethoxy-1,4,5,6-tetrahydro-7,9-etheno-3-benzazecine-3-(2H)-carboxylate

Base Information

Chemical Name:phenyl 10,11-dimethoxy-1,4,5,6-tetrahydro-7,9-etheno-3-benzazecine-3-(2H)-carboxylate
CAS No.:96165-83-2
Molecular Formula:C₂₄H₂₅NO₄
Molecular Weight:391.467
Hs Code.:

Synonyms:phenyl 10,11-dimethoxy-1,4,5,6-tetrahydro-7,9-etheno-3-benzazecine-3-(2H)-carboxylate

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Chemical Property of phenyl 10,11-dimethoxy-1,4,5,6-tetrahydro-7,9-etheno-3-benzazecine-3-(2H)-carboxylate

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Technology Process of phenyl 10,11-dimethoxy-1,4,5,6-tetrahydro-7,9-etheno-3-benzazecine-3-(2H)-carboxylate

There total 8 articles about phenyl 10,11-dimethoxy-1,4,5,6-tetrahydro-7,9-etheno-3-benzazecine-3-(2H)-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 96165-85-4
8,9-dimethoxy-2,3,5,6,11a,11b-hexahydro-1H-benzopyrido<3,2,1-ij>quinoline

: 1885-14-9
phenyl chloroformate

: 96165-83-2
phenyl 10,11-dimethoxy-1,4,5,6-tetrahydro-7,9-etheno-3-benzazecine-3-(2H)-carboxylate

Guidance literature:: With potassium carbonate; In ethanol; chloroform; 1.) 5 h, reflux; 2.) 12 h, RT;
DOI:10.1021/ja00299a025

Reference yield:

: 55302-27-7
9,10-dimethoxy-3,4,6,7-tetrahydro-2H-benzo quinolizine

: 96165-83-2
phenyl 10,11-dimethoxy-1,4,5,6-tetrahydro-7,9-etheno-3-benzazecine-3-(2H)-carboxylate

Guidance literature:: Multi-step reaction with 7 steps

1: 85 percent / 0.5 h / 120 °C

2: 100 percent / NaBH₄ / ethanol / 1 h / Ambient temperature

3: 94 percent / 1 M HCl / 48 h / Ambient temperature

4: 72 percent / H₂SO₄, 20 percent SO₃ / 0.17 h / 80 °C

5: NaBH₄ / ethanol / 20 °C

6: 1 M HCl / H₂O / Heating

7: 89 percent / anhydrous K₂CO₃ / ethanol; CHCl₃ / 1.) 5 h, reflux; 2.) 12 h, RT

With hydrogenchloride; sodium tetrahydroborate; sulfuric acid; sulfur trioxide; potassium carbonate; In ethanol; chloroform; water;
DOI:10.1021/ja00299a025

Reference yield:

: 96165-96-7
(10aR,10bR)-7,8-Dimethoxy-2,3,4,5,9,10,10a,10b-octahydro-1H-3a-aza-pyren-9-ol

: 96165-83-2
phenyl 10,11-dimethoxy-1,4,5,6-tetrahydro-7,9-etheno-3-benzazecine-3-(2H)-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1 M HCl / H₂O / Heating

2: 89 percent / anhydrous K₂CO₃ / ethanol; CHCl₃ / 1.) 5 h, reflux; 2.) 12 h, RT

With hydrogenchloride; potassium carbonate; In ethanol; chloroform; water;
DOI:10.1021/ja00299a025