benzyltri(n-propyl)tin

Base Information

• Chemical Name: benzyltri(n-propyl)tin
• CAS No.: 74903-72-3
• Molecular Formula: C₁₆H₂₈Sn
• Molecular Weight: 339.108
• Mol file: 74903-72-3.mol

Synonyms:benzyltri(n-propyl)tin

Chemical Property of benzyltri(n-propyl)tin

Chemical Property:

Purity/Quality:

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Technology Process of benzyltri(n-propyl)tin

There total 1 articles about benzyltri(n-propyl)tin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

benzyl bromide (100-39-0) + tripropyltin chloride (2279-76-7) → benzyltri(n-propyl)tin (74903-72-3)

Guidance literature:

With Zn; NH₄Cl; In tetrahydrofuran; water; air; addn. of organotin (1 equiv.) to suspension of Zn-powder (2 equivs.) in satd. soln. of NH4Cl in H2O:THF, dropwise addn. of benzyl bromide (2 equivs.) with rate maintaining gentle reflux, stirring with cooling toroom temp. for 30 min; sepn. of org. layer, evapn., distillation (vac.); elem. anal.;

DOI:10.1021/om9507742

Reference yield:

benzyltri(n-propyl)tin (74903-72-3) → tripropyl tin (1+); iodide (7342-45-2) + iodomethylbenzene (620-05-3)

Guidance literature:

With iodine; In methanol; mixture was left in the dark overnight at 298 K; poured into water, extrd. (CCl4), dried (Na2SO4), NMR; Kinetics;

upstream raw materials:

benzyl bromide

tripropyltin chloride

Downstream raw materials:

tripropyl tin ⁽¹⁺⁾; iodide

iodomethylbenzene

Refernces