N-((4-methylthio)benzyl)benzenamine

Base Information

• Chemical Name: N-((4-methylthio)benzyl)benzenamine
• CAS No.: 723753-86-4
• Molecular Formula: C₁₄H₁₅NS
• Molecular Weight: 229.346
• Mol file: 723753-86-4.mol

Synonyms:N-((4-methylthio)benzyl)benzenamine

Chemical Property of N-((4-methylthio)benzyl)benzenamine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of N-((4-methylthio)benzyl)benzenamine

There total 6 articles about N-((4-methylthio)benzyl)benzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(4-methylsulfanylbenzylidene)phenylamine (22116-67-2) → N-((4-methylthio)benzyl)benzenamine (723753-86-4)

Guidance literature:

With (4-Ph)Triaz(NHPⁱPr₂)₂Mn(CO)₂Br; potassium tert-butylate; hydrogen; In tetrahydrofuran; at 50 ℃; for 4h; under 15001.5 Torr; chemoselective reaction; Glovebox; Autoclave; Sealed tube;

DOI:10.1021/jacs.9b05024

Reference yield: 96.0%

4-(methylthio)benzyl alcohol (3446-90-0) + aniline (62-53-3) → N-((4-methylthio)benzyl)benzenamine (723753-86-4)

Guidance literature:

With 1,10-Phenanthroline; tungsten hexacarbonyl; potassium tert-butylate; In 1,4-dioxane; at 130 ℃; for 24h;

DOI:10.1002/cssc.202002830

Reference yield: 96.0%

→ N-((4-methylthio)benzyl)benzenamine (723753-86-4)

Guidance literature:

With [2,2]bipyridinyl; tungsten hexacarbonyl; potassium tert-butylate; In 1,4-dioxane; at 130 ℃; for 24h; Schlenk technique; Inert atmosphere;

upstream raw materials:

aniline

4-(Methylthio)benzaldehyde

methyl-phenyl-thioether

benzyl azide

Downstream raw materials:

(4-methylsulfanylbenzylidene)phenylamine