Pt⁽²⁺⁾CO₃^(2-)(C₆H₅)2PCH₂CH₂P(C₆H₅)2=Pt(CO₃)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

Base Information

Chemical Name:Pt⁽²⁺⁾*CO₃^(2-)*(C₆H₅)2PCH₂CH₂P(C₆H₅)2=Pt(CO₃)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)
CAS No.:25787-92-2
Molecular Formula:CO₃*C₂₆H₂₄P₂*Pt
Molecular Weight:653.513
Hs Code.:

Pt<sup>(2+)</sup>*CO<sub>3</sub><sup>(2-)</sup>*(C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2=Pt(CO<sub>3</sub>)((C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)

Synonyms:Pt⁽²⁺⁾*CO₃^(2-)*(C₆H₅)2PCH₂CH₂P(C₆H₅)2=Pt(CO₃)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

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Chemical Property of Pt⁽²⁺⁾*CO₃^(2-)*(C₆H₅)2PCH₂CH₂P(C₆H₅)2=Pt(CO₃)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

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Technology Process of Pt⁽²⁺⁾*CO₃^(2-)*(C₆H₅)2PCH₂CH₂P(C₆H₅)2=Pt(CO₃)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

There total 5 articles about Pt⁽²⁺⁾*CO₃^(2-)*(C₆H₅)2PCH₂CH₂P(C₆H₅)2=Pt(CO₃)((C₆H₅)2PCH₂CH₂P(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 438188-08-0
Pt((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OSi(CH₂CH₃)3)2

: 124-38-9,18923-20-1
carbon dioxide

: 25787-92-2
(1,2-bis(diphenylphosphane)ethane)carbonateplatinum(II)

Guidance literature:: With water; In benzene; byproducts: (CH3CH2)3SiOH; (N2); bubbling CO through a soln. of platinum complex in C6H6 for 30 min; filtration, washing with C6H6;

Reference yield: 92.0%

: 256636-17-6
Pt(O₂CN(C₂H₅)2)2((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

: 7732-18-5
water

: 25787-92-2
(1,2-bis(diphenylphosphane)ethane)carbonateplatinum(II)

Guidance literature:: In tetrahydrofuran; toluene; byproducts: HNEt2, CO2; (N2); filtration, drying (vac.); elem. anal.;

Reference yield: 83.0%

: 83095-83-4,14647-25-7
[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

: 124-38-9,18923-20-1
carbon dioxide

: 25787-92-2
(1,2-bis(diphenylphosphane)ethane)carbonateplatinum(II)

Guidance literature:: With water; NaO-i-Pr; In tetrahydrofuran; byproducts: NaCl; Ar-atmosphere; slow addn. of propoxide to Pt-complex, standing for 3 h, addn. of 5 equiv. water, bubbling CO2, standing under CO2 overnight; collection, washing, drying;
DOI:10.1021/ic9603159