[Ni(1,2-bis(di-isopropylphosphino)ethane)(η²-C,C-styrene)]

Base Information

• Chemical Name: [Ni(1,2-bis(di-isopropylphosphino)ethane)(η²-C,C-styrene)]
• CAS No.: 1196586-82-9
• Molecular Formula: C₂₂H₄₀NiP₂
• Molecular Weight: 425.197
• Mol file: 1196586-82-9.mol

Synonyms:[Ni(1,2-bis(di-isopropylphosphino)ethane)(η²-C,C-styrene)]

Chemical Property of [Ni(1,2-bis(di-isopropylphosphino)ethane)(η²-C,C-styrene)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ni(1,2-bis(di-isopropylphosphino)ethane)(η²-C,C-styrene)]

There total 10 articles about [Ni(1,2-bis(di-isopropylphosphino)ethane)(η²-C,C-styrene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + [(bis(diisopropylphosphino)ethane)Ni(H)]2 (130777-67-2) → [Ni(1,2-bis(di-isopropylphosphino)ethane)(η2-C,C-styrene)] (1196586-82-9)

Guidance literature:

In tetrahydrofuran; methanol; for 0.333333h; Time; Schlenk technique; Inert atmosphere;

DOI:10.1021/om300819d

Reference yield: 65.0%

[Ni(Me)(C2H4Ph)(1,2-bis(diisopropylphosphino)ethane)] (1196586-81-8) + [Ni(Me)(CH(Me)Ph)(1,2-bis(diisopropylphosphino)ethane)] (1196586-84-1) → [Ni(1,2-bis(di-isopropylphosphino)ethane)(η2-C,C-styrene)] (1196586-82-9)

Guidance literature:

In tetrahydrofuran; byproducts: CH4; (N2); Schlenk technique; soln. of Ni complex in THF was heated at 60°C for 1.5 h; evapd. (vac.); extd. (Et2O); crystd. at -20°C; elem. anal.;

DOI:10.1021/om900400s

Reference yield:

[Ni(1,2-bis(diisopropylphosphino)ethane)(η2-PhCHNCH2Ph)] (946122-62-9) → [Ni(1,2-bis(di-isopropylphosphino)ethane)(η2-C,C-styrene)] (1196586-82-9) + benzaldehyde (100-52-7)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrahydrofuran

2: tetrahydrofuran

3: tetrahydrofuran

In tetrahydrofuran;

DOI:10.1021/om300980n

upstream raw materials:

[Ni(Me)(C₂H₄Ph)(1,2-bis(diisopropylphosphino)ethane)]

[Ni(Me)(CH(Me)Ph)(1,2-bis(diisopropylphosphino)ethane)]

bis(phenethyl)magnesium

[Ni(CH₃)(F)(1,2-bis(diisopropylphosphino)ethane)]

Downstream raw materials:

styrene

[Ni(η2-benzaldehyde)(1,2-bis(diisopropylphosphino)ethane)]

[(dippe)Ni(η²-C,O-acetophenone)]

[Ni(1,2-bis(diisopropylphosphino)ethane)(η2-PhCHNCH2Ph)]