Pericyclocamphanone

Base Information

• Chemical Name: Pericyclocamphanone
• CAS No.: 875-99-0
• Molecular Formula: C₁₀H₁₄O
• Molecular Weight: 150.221
• Hs Code.: 2914299000
• DSSTox Substance ID: DTXSID801007607
• Nikkaji Number: J1.014.193A
• Mol file: 875-99-0.mol

Synonyms:beta-pericyclocamphanone;pericyclocamphanone

Chemical Property of Pericyclocamphanone

Chemical Property:

• Vapor Pressure: 0.225mmHg at 25°C
• Melting Point: 126-130 °C(lit.)
• Refractive Index: 1.537
• Boiling Point: 207.5 °C at 760 mmHg
• Flash Point: 72.2 °C
• PSA: 62.60000
• Density: 1.105 g/cm³
• LogP: 2.10670
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 150.104465066
• Heavy Atom Count: 11
• Complexity: 266

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(C2C3C2C(=O)C1(C3)C)C

Technology Process of Pericyclocamphanone

There total 18 articles about Pericyclocamphanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

3-diazocamphor (14487-70-8) → cyclocamphanone (875-99-0)

Guidance literature:

With lithium perchlorate; silver; silver(l) oxide; In water; acetonitrile; at 26.85 ℃; Electrochemical reaction;

DOI:10.1021/ol052981w

Reference yield: 70.0%

3-diazocamphor (14487-70-8) → Cyclocamphanon (6069-78-9,70614-32-3,875-99-0)

Guidance literature:

In water; Product distribution; microwave irradiation;

DOI:10.1021/jo010951a

Reference yield:

(1R,4S)-3-diazobornan-2-one (70614-31-2) → (1S)-3.3.4-trimethyl-2.6-cyclo-norbornanone-(5) (875-99-0,6069-78-9,70614-32-3)

Guidance literature:

With copper;

upstream raw materials:

3-diazocamphor

(1S)-3.3.4-trimethyl-2,6-cyclo-norbornanone-⁽⁵⁾-hydrazone

(1R,4S)-3-diazobornan-2-one

silver(I) acetate

Downstream raw materials:

Isotricyclen