Silver acetate

Base Information

• Chemical Name: Silver acetate
• CAS No.: 563-63-3
• Deprecated CAS: 26088-37-9
• Molecular Formula: C2H3AgO2
• Molecular Weight: 166.913
• Hs Code.: 28432900
• European Community (EC) Number: 209-254-9
• UNII: 19PPS85F9H
• DSSTox Substance ID: DTXSID8032041
• Nikkaji Number: J43.267I
• Wikipedia: Silver_acetate
• Wikidata: Q416750
• ChEMBL ID: CHEMBL4464576
• Mol file: 563-63-3.mol

Synonyms:silver acetate

Chemical Property of Silver acetate

Chemical Property:

• Appearance/Colour: Off-white/brown crystalline powder
• Vapor Pressure: 13.9mmHg at 25°C
• Melting Point: decomposes [STR93]
• Boiling Point: 117.1°C at 760 mmHg
• Flash Point: 40°C
• PSA: 26.30000
• Density: 3.25 g/cm³
• LogP: 0.01380
• Storage Temp.: Store below +30°C.
• Sensitive.: Light Sensitive
• Solubility.: 10.2g/l
• Water Solubility.: 10.2 g/L (20 ºC)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 165.91840
• Heavy Atom Count: 5
• Complexity: 25.5

Purity/Quality:

99.9% ^*data from raw suppliers

Silver Acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,N
• Statements: 36/37/38-50
• Safety Statements: 26-36-37/39-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Acids, Metal Salts
• Canonical SMILES: CC(=O)[O-].[Ag+]
• Description: Silver acetate (C2H3AgO2) is a photosensitive, white, crystalline solid which is widely used in the laboratory. As a source of silver ions lacking an oxidizing anion, it is a useful reagent for direct ortho-arylation, and for conversion of organohalogen compounds into alcohols, etc. It also serves as a catalyst to effectively catalyze the cycloaddition reactions of isocyanoacetates with a variety of olefins. It can be employed in the novel preparation of highly reflective, conductive silvered polymer films.Besides, it has applications in some antismoking drugs and in the health field, in which the products containing silver acetate have been applied in spray, and lozenges to deter smokers from smoking. When mixed with smoke, the silver acetate creates an unpleasant metallic taste in the smoker's mouth, thereby preventing them from smoking. Silver acetate is an organic compound with the empirical formula CH3COOAg (or AgC2H3O2). It is a photosensitive, white crystalline solid. It is a useful reagent in the laboratory as a water soluble source of silver lacking an oxidizing anion. It has been used in some antismoking drugs.
• Uses: Oxidizing agent for use in liquid ammonia: Kline, Kershner, Inorg. Chem. 5, 932 (1966). In the health field, silver acetate-containing products have been used in gum, spray, and lozenges to deter smokers from smoking. The silver in these products, when mixed with smoke, creates an unpleasant metallic taste in the smoker's mouth, thus deterring them from smoking. Lozenges containing 2.5 mg of silver acetate showed "modest efficacy" on 500 adult smokers tested over a three-month period. However, over a period of 12 months, prevention failed. In 1974, silver acetate was first introduced in Europe as an over-thecounter smoking-deterrent lozenge (Repaton) and then three years later as a chewing gum (Tabmint). It is a reagent in the laboratory as a source of silver ions lacking an oxidizing anion. It is a reagent for direct ortho-arylation, and for conversion of organohalogen compounds into alcohols. Woodward cis-hydroxylation reaction employs silver acetate and iodine for selective conversin of alkenes into cis-diols. Silver acetate is the more preferred reagent for facile carbonylation of primary and secondary amines. It is also employed in the preparation of highly reflective, conductive silvered polymer films.

Technology Process of Silver acetate

There total 23 articles about Silver acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

acetic acid (64-19-7,77671-22-8) + silver(l) oxide (20667-12-3) → silver(I) acetate (563-63-3)

Guidance literature:

at 50 ℃; for 0.0833333h;

DOI:10.1021/acs.joc.9b00605

Reference yield: 91.0%

sodium acetate (127-09-3) + silver nitrate → silver(I) acetate (563-63-3)

Guidance literature:

With acetic acid; In water; at 23 ℃;

DOI:10.1039/c5cc02227d

Reference yield: 75.0%

Pd[(μ-O2CMe)2Ag(HO2CMe)2]2 (1308661-15-5) + 1,10-phenanthroline hydrate (5144-89-8) → (1,10-phenanthroline)-palladium(II) acetate (35679-81-3) + silver(I) acetate (563-63-3)

Guidance literature:

In benzene; benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (1:1 molar ratio), mixt. stirred at room temp. for 30 min; ppt. filtered off, concd., pptd. (heptane), dried, elem. anal.;

DOI:10.1016/j.ica.2011.02.003

upstream raw materials:

2,4,6-trimethyl-[1,3,5]dioxathiane

LACTIC ACID

water

acetic acid

Downstream raw materials:

2,3-Dimethyl-2-butene

n-octyl acetate

2-nonanyl acetate

Allyl acetate

Refernces

• 1、 Logvinenko,Polunina,Mikhailov,Mikhailov,Bokhonov. "Study of thermal decomposition of silver acetate". . p. 813 - 816. Retrieved 2007.
• 2、 Touller, J. C.,Tremillon, B.. "". . p. 115 - 134. Retrieved 1970.
• 3、 Kline, Robert J.,Kershner, Carl J.. "The oxidation of uranium(IV) acetate by silver acetate in liquid ammonia". . p. 932 - 934. Retrieved 1966.
• 4、 Holmes, H. N.. "". . p. 743 - 773. Retrieved 1917.
• 5、 Bilibin, A. Yu,Fetin, P. A.,Fetina, V. I.,Lezov, A. A.,Zorin, I. M.. "Impact of counterions on micelle formation and polymerization of 11-acryloyloxyundecyltrimethylammonium surfactants". . . Retrieved 2020/04/20.
• 6、 Stephens, David E.,Lakey-Beitia, Johant,Chavez, Gabriel,Ilie, Carla,Arman, Hadi D.,Larionov, Oleg V.. "Experimental and mechanistic analysis of the palladium-catalyzed oxidative C8-selective C-H homocoupling of quinoline N-oxides". supporting information. p. 9507 - 9510. Retrieved 2015/06/08.