Technology Process of 2,4-di-O-benzyl-6-deoxy-3-O-methyl-α-L-talopyranoside
There total 16 articles about 2,4-di-O-benzyl-6-deoxy-3-O-methyl-α-L-talopyranoside which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
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Multi-step reaction with 7 steps
1: NaBH4 / methanol / 1.) r.t., 20 min; 2.) reflux, 10 min
2: 1.) RuO4; 2.) NaBH4 / 2.) MeOH
3: 92 percent / 1 M NaOMe / CH2Cl2; methanol / 5 h / Ambient temperature
4: 86 percent / NaH / dimethylformamide
5: 92 percent / water / acetic acid / 1 h / 80 °C
6: 32 percent / dibutyltin oxide, tetrabutylammonium bromide / benzene / 23 h / Heating
7: 88 percent / NaH / dimethylformamide
With
sodium tetrahydroborate; ruthenium tetroxide; tetrabutylammomium bromide; water; sodium methylate; sodium hydride; di(n-butyl)tin oxide;
In
methanol; dichloromethane; acetic acid; N,N-dimethyl-formamide; benzene;
DOI:10.1016/0008-6215(83)84006-3
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 1.) potassium periodate, potassium carbonate, RhO2; 2.) 2-propanol / 1.) 7 h, r.t.; 2.) r.t., 20 min
2: NaBH4 / methanol / 1.) r.t., 20 min; 2.) reflux, 10 min
3: 86 percent / NaH / dimethylformamide
4: 92 percent / water / acetic acid / 1 h / 80 °C
5: 32 percent / dibutyltin oxide, tetrabutylammonium bromide / benzene / 23 h / Heating
6: 88 percent / NaH / dimethylformamide
With
rhodium(IV) oxide; sodium tetrahydroborate; potassium metaperiodate; tetrabutylammomium bromide; water; sodium hydride; di(n-butyl)tin oxide; potassium carbonate; isopropyl alcohol;
In
methanol; acetic acid; N,N-dimethyl-formamide; benzene;
DOI:10.1016/0008-6215(83)84006-3
