(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

Base Information

Chemical Name:(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene
CAS No.:175356-63-5
Molecular Formula:C₅₉H₉₁NO₇Si₂
Molecular Weight:982.545
Hs Code.:

(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

Synonyms:(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

Suppliers and Price of (2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

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Chemical Property of (2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

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Technology Process of (2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

There total 1 articles about (2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 175356-54-4
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-10-methoxy-4,6,8,12-tetramethyl-2,6-tridecadien-9,13-diol

: 74-88-4
methyl iodide

: 175356-63-5
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

Guidance literature:: With potassium hydride; In tetrahydrofuran; at 0 ℃;
DOI:10.1021/jo00030a007

Reference yield: 98.0%

: 175356-63-5
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

: 175356-64-6
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadien-1,5-diol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 2h; Ambient temperature;
DOI:10.1016/0040-4020(95)01107-2

Reference yield:

: 175356-63-5
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

: 123115-02-6
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-5-tert-butyldimethylsilyloxy-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxy-phenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadien-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / TBAF / tetrahydrofuran / 2 h / Ambient temperature

2: 99 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -20 °C

3: 95 percent / aq. trifluoroacetic acid / 3 h / 0 °C

With 2,6-dimethylpyridine; tetrabutyl ammonium fluoride; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0040-4020(95)01107-2