chloro(η6-p-cymene)(diphenyl(o-N-methylanilido)phosphine)ruthenium(II)

Base Information

Chemical Name:chloro(η6-p-cymene)(diphenyl(o-N-methylanilido)phosphine)ruthenium(II)
CAS No.:1224509-20-9
Molecular Formula:C₂₉H₃₁ClNPRu
Molecular Weight:561.069
Hs Code.:

Synonyms:chloro(η6-p-cymene)(diphenyl(o-N-methylanilido)phosphine)ruthenium(II)

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Chemical Property of chloro(η6-p-cymene)(diphenyl(o-N-methylanilido)phosphine)ruthenium(II)

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Technology Process of chloro(η6-p-cymene)(diphenyl(o-N-methylanilido)phosphine)ruthenium(II)

There total 1 articles about chloro(η6-p-cymene)(diphenyl(o-N-methylanilido)phosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1224509-14-1,1224509-19-6
dichloro(η6-p-cymene)(diphenyl(o-N-methylanilinyl)phosphine)ruthenium(II)

: 1224509-20-9
chloro(η6-p-cymene)(diphenyl(o-N-methylanilido)phosphine)ruthenium(II)

Guidance literature:: With triethylamine; In benzene; byproducts: triethylammonium chloride; under Ar; to a soln. of Ru-contg. compd. (638E-6 mol) in benzene was added with stirring a 10-fold excess of NEt3 (6.4 mmol); addn. of deoxygenated water; stirring for 5 min; the org. layer was transferred to a Schlenk tube under Ar; the solvent and residual NEt3 were removed in vac.; addn. of THF and Et2O; the solid was collected by filtration, washed with n-pentane and dried in vac.; elem. anal.;
DOI:10.1021/ic100165t

Reference yield: 60.0%

: 1224509-20-9
chloro(η6-p-cymene)(diphenyl(o-N-methylanilido)phosphine)ruthenium(II)

: 925-90-6
ethylmagnesium bromide

: 1314186-96-3
ethyl(η6-p-cymene)(P,N-diphenyl(o-N-methylanilido)phosphine)ruthenium(II)

Guidance literature:: In benzene; (Ar) to soln. Ru complex in benzene EtMgBr in Et2O was added, stirred for 5 min; solvent was removed in vacuo, benzene was added, stirred, filtered through Celite, soln. was concd. in vacuo and layered with n-pentane, 18 h, ppt. was dried in vacuo; elem. anal.;
DOI:10.1021/om2004173

Reference yield:

: 16940-66-2
sodium tetrahydroborate

: 1224509-20-9
chloro(η6-p-cymene)(diphenyl(o-N-methylanilido)phosphine)ruthenium(II)

: 1314186-95-2
hydrido(η6-p-cymene)(P,N-diphenyl(o-N-methylanilido)phosphine)ruthenium(II)

Guidance literature:: In methanol; (Ar) soln. Ru complex and NaBH4 in MeOH was stirred for 30 min; solvent was removed in vacuo, benzene was added, stirred for 10 min, supernatant was filtered through Celite, solvent was removed in vacuo;
DOI:10.1021/om2004173