5-(methoxycarbonyl)-3-<(benzyloxy)carbonyl>-2,3,5-oxadiazabicyclo<2.2.2>oct-7ene

Base Information

Chemical Name:5-(methoxycarbonyl)-3-<(benzyloxy)carbonyl>-2,3,5-oxadiazabicyclo<2.2.2>oct-7ene
CAS No.:94936-55-7
Molecular Formula:C₁₅H₁₆N₂O₅
Molecular Weight:304.302
Hs Code.:

Synonyms:5-(methoxycarbonyl)-3-<(benzyloxy)carbonyl>-2,3,5-oxadiazabicyclo<2.2.2>oct-7ene

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Chemical Property of 5-(methoxycarbonyl)-3-<(benzyloxy)carbonyl>-2,3,5-oxadiazabicyclo<2.2.2>oct-7ene

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Technology Process of 5-(methoxycarbonyl)-3-<(benzyloxy)carbonyl>-2,3,5-oxadiazabicyclo<2.2.2>oct-7ene

There total 4 articles about 5-(methoxycarbonyl)-3-<(benzyloxy)carbonyl>-2,3,5-oxadiazabicyclo<2.2.2>oct-7ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 3426-71-9
Benzyl N-hydroxycarbamate

: 33707-36-7
1-(methoxycarbonyl)-1,2-dihydropyridine

: 94936-55-7
5-(methoxycarbonyl)-3-<(benzyloxy)carbonyl>-2,3,5-oxadiazabicyclo<2.2.2>oct-7ene

: 94936-50-2
3-Oxa-2,5-diaza-bicyclo[2.2.2]oct-7-ene-2,5-dicarboxylic acid 2-benzyl ester 5-methyl ester

: 96212-83-8
6-hydroxy-1-(methoxycarbonyl)-3(R(S))--1,2,3,6-tetrahydropyridine

Guidance literature:: With tetraethylammonium metaperiodate; In dichloromethane; at -78 - 25 ℃; for 6h; Yields of byproduct given;
DOI:10.1021/jo00212a015

Reference yield:

: 3426-71-9
Benzyl N-hydroxycarbamate

: 33707-36-7
1-(methoxycarbonyl)-1,2-dihydropyridine

: 94936-55-7,96212-77-0
methyl 3-benzyloxycarbonyl-2-oxa-3,5-diazabicyclo<2.2.2>oct-7-ene-5-carboxylate

: methyl 2-benzyloxycarbonyl-3-oxa-2,5-diazabicyclo<2.2.2>oct-7-ene-5-carboxylate

Guidance literature:: With tetrapropylammonium periodate; In dichloromethane; at 0 ℃; for 1h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1002/hlca.19870700308

Reference yield:

: 3426-71-9
Benzyl N-hydroxycarbamate

: 94936-55-7,96212-77-0
methyl 3-benzyloxycarbonyl-2-oxa-3,5-diazabicyclo<2.2.2>oct-7-ene-5-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: tetra-n-propylammonium periodate / CH₂Cl₂ / 0 °C

2: CH₂Cl₂ / 0 °C

With tetrapropylammonium periodate; In dichloromethane;
DOI:10.1016/S0040-4039(01)81481-7