[RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

Base Information

• Chemical Name: [RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]
• CAS No.: 911061-41-1
• Molecular Formula: C₄₃H₄₅ClN₂P₂Ru
• Molecular Weight: 788.314
• Mol file: 911061-41-1.mol

Synonyms:[RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

Chemical Property of [RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

There total 1 articles about [RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

RuCl2(1,4-bis(diphenylphosphino)butane)(PPh3) (88496-72-4) + N,N-dimethyl-2-aminomethyl-6-(4-methylphenyl)pyridine (911061-46-6) → [RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (911061-41-1)

Guidance literature:

With triethylamine; In isopropyl alcohol; under Ar atm. to suspn. Ru complex in 2-propanol ligand and Et3N were added and refluxed overnight; ppt. was filtered, washed with MeOH and dried in vacuo; elem. anal.;

DOI:10.1021/om060408q

Reference yield: 82.0%

[RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (911061-41-1) + 4-fluoro-3-methylphenol (452-70-0) + potassium isopropoxide (6831-82-9) → [Ru(4-fluoro-3-methylphenolate)(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (1174935-95-5,1174936-02-7)

Guidance literature:

In isopropyl alcohol; toluene; byproducts: KCl, (CH3)2CHOH; (Ar, Schlenk technique); addn. of potassium isopropoxide in isopropanol to ruthenium compd. in toluene, stirring at 60°C for 2 h, keepingat -20°C for 2 h, filtration through celite, addn. of phenol der iv., stirring at room temp. for 0.5 h; evapn., addn. of toluene, evapn., drying in vac., elem. anal.;

DOI:10.1021/om900274r

Reference yield: 74.0%

[RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (911061-41-1) + potassium tert-butylate (865-47-4) → [Ru(tert-butoxide)(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (1174935-96-6,1174936-03-8)

Guidance literature:

In toluene; tert-butyl alcohol; byproducts: KCl; (Ar, Schlenk technique); addn. of potassium tert-butoxide to suspn. of ruthenium compd. in 1:1 toluene/tert-butanol, stirring at room temp. for 2 h; keeping at -20°C overnight, filtration through celite, evapn., addn. of toluene, concg., addn. of pentane, filtration, drying in vac., elem. anal.;

DOI:10.1021/om900274r

upstream raw materials:

RuCl2(1,4-bis(diphenylphosphino)butane)(PPh3)

N,N-dimethyl-2-aminomethyl-6-(4-methylphenyl)pyridine

Downstream raw materials:

[RuH(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

[Ru(tert-butoxide)(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

[Ru(4-fluoro-3-methylphenolate)(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]