[RuH(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

Base Information

• Chemical Name: [RuH(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]
• CAS No.: 911061-43-3
• Molecular Formula: C₄₃H₄₆N₂P₂Ru
• Molecular Weight: 753.869
• Mol file: 911061-43-3.mol

Synonyms:

Chemical Property of [RuH(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuH(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

There total 3 articles about [RuH(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

[RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (911061-41-1) + sodium isopropylate (683-60-3) → [RuH(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (911061-43-3)

Guidance literature:

In isopropyl alcohol; toluene; byproducts: acetone; under Ar atm. to suspn. Ru complex in toluene soln. i-PrONa in i-PrOH was added and stirred for 2 h at 60°C, soln. was concd. and stirredat room temp. for 30 min; soln. was filtered and evapd. in vacuo, residue was extd. with pentane and dried in vacuo; elem. anal.;

DOI:10.1021/om060408q

Reference yield:

RuCl2(1,4-bis(diphenylphosphino)butane)(PPh3) (88496-72-4) + N,N-dimethyl-2-aminomethyl-6-(4-methylphenyl)pyridine (911061-46-6) → [RuH(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (911061-43-3)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / isopropyl alcohol

2: toluene; isopropyl alcohol

With triethylamine; In isopropyl alcohol; toluene;

DOI:10.1021/om060408q

Reference yield:

[Ru(isopropoxide)(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (911061-47-7) → [RuH(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)] (911061-43-3)

Guidance literature:

In not given; (Ar, Schlenk technique); slow conversion of ruthenium compd.;

DOI:10.1021/om900274r

upstream raw materials:

[RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

sodium isopropylate

[Ru(isopropoxide)(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]

RuCl2(1,4-bis(diphenylphosphino)butane)(PPh3)