bicyclo[9.2.2]pentadeca-1(13),11,14-trien-5-one

Base Information

• Chemical Name: bicyclo[9.2.2]pentadeca-1(13),11,14-trien-5-one
• CAS No.: 96953-15-0
• Molecular Formula: C₁₅H₂₀O
• Molecular Weight: 216.323
• Mol file: 96953-15-0.mol

Synonyms:[9]paracyclophan-4-one

Chemical Property of bicyclo[9.2.2]pentadeca-1(13),11,14-trien-5-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bicyclo[9.2.2]pentadeca-1(13),11,14-trien-5-one

There total 8 articles about bicyclo[9.2.2]pentadeca-1(13),11,14-trien-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

glutaric anhydride, (108-55-4) → [9]paracyclophan-4-one (96953-15-0)

Guidance literature:

Multi-step reaction with 4 steps

1: (i) AlCl₃, (ii) N₂H₄*H₂O, KOH, diethylene glycol, (iii) /BRN= 1098229/, H₂SO₄

2: AlCl₃ / CH₂Cl₂

3: (i) N₂H₄*H₂O, KOH, diethylene glycol, (ii) /BRN= 1098229/, H₂SO₄

4: (i) Na, xylene, (ii) ZnCl₂, propane-1,3-dithiol, benzene, (iii) HgCl₂, CdCO₃, H₂O, acetone

With aluminium trichloride; In dichloromethane;

DOI:10.1021/ja00891a009

Reference yield:

5-phenyl-n-valeric acid methyl ester (20620-59-1) → [9]paracyclophan-4-one (96953-15-0)

Guidance literature:

Multi-step reaction with 3 steps

1: AlCl₃ / CH₂Cl₂

2: (i) N₂H₄*H₂O, KOH, diethylene glycol, (ii) /BRN= 1098229/, H₂SO₄

3: (i) Na, xylene, (ii) ZnCl₂, propane-1,3-dithiol, benzene, (iii) HgCl₂, CdCO₃, H₂O, acetone

With aluminium trichloride; In dichloromethane;

DOI:10.1021/ja00891a009

Reference yield:

benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → [9]paracyclophan-4-one (96953-15-0)

Guidance literature:

Multi-step reaction with 4 steps

1: (i) AlCl₃, (ii) N₂H₄*H₂O, KOH, diethylene glycol, (iii) /BRN= 1098229/, H₂SO₄

2: AlCl₃ / CH₂Cl₂

3: (i) N₂H₄*H₂O, KOH, diethylene glycol, (ii) /BRN= 1098229/, H₂SO₄

4: (i) Na, xylene, (ii) ZnCl₂, propane-1,3-dithiol, benzene, (iii) HgCl₂, CdCO₃, H₂O, acetone

With aluminium trichloride; In dichloromethane;

DOI:10.1021/ja00891a009

upstream raw materials:

5-[4-(3-methoxycarbonyl-propyl)-phenyl]-valeric acid methyl ester

5-[4-(3-carboxy-propyl)-phenyl]-valeric acid

4-[4-(4-ethoxycarbonyl-butyl)-phenyl]-4-oxo-butyric acid

glutaric anhydride,

Downstream raw materials:

4-(Phthalsaeure)-⁽⁹⁾-paracyclophanester