Technology Process of IrH2((CH3)2CHI)2(P(C6H5)3)2(1+)*SbF6(1-)=(IrH2((CH3)2CHI)2(P(C6H5)3)2)SbF6
There total 1 articles about IrH2((CH3)2CHI)2(P(C6H5)3)2(1+)*SbF6(1-)=(IrH2((CH3)2CHI)2(P(C6H5)3)2)SbF6 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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With
hydrogen;
In
dichloromethane;
i-PrI was added to a CH2Cl2 soln. of Ir-complex at 0°C under N2 in the dark, N2 was replaced by an H2 atmosphere, mixt. stirred for 30 min; Et2O and pentane were added under H2 atmosphere, ppt. was filtered, washed with Et2O, dried in vacuo, recrystd. from CH2Cl2-Et2O-pentane, washed with pentane, dried in vacuo;
DOI:10.1021/om00153a035