3-{1-[(tert-butyldimethylsilyl)oxy]prop-2-enyl}-3-[(4-methoxybenzyloxy)methyl]-oxetane

Base Information

Chemical Name:3-{1-[(tert-butyldimethylsilyl)oxy]prop-2-enyl}-3-[(4-methoxybenzyloxy)methyl]-oxetane
CAS No.:1450912-13-6
Molecular Formula:C₂₁H₃₄O₄Si
Molecular Weight:378.584
Hs Code.:

Synonyms:3-{1-[(tert-butyldimethylsilyl)oxy]prop-2-enyl}-3-[(4-methoxybenzyloxy)methyl]-oxetane

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Chemical Property of 3-{1-[(tert-butyldimethylsilyl)oxy]prop-2-enyl}-3-[(4-methoxybenzyloxy)methyl]-oxetane

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Technology Process of 3-{1-[(tert-butyldimethylsilyl)oxy]prop-2-enyl}-3-[(4-methoxybenzyloxy)methyl]-oxetane

There total 6 articles about 3-{1-[(tert-butyldimethylsilyl)oxy]prop-2-enyl}-3-[(4-methoxybenzyloxy)methyl]-oxetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1450912-12-5
1-{3-((4-methoxybenzyloxy)methyl)-oxetan-3-yl}prop-2-en-1-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1450912-13-6
3-{1-[(tert-butyldimethylsilyl)oxy]prop-2-enyl}-3-[(4-methoxybenzyloxy)methyl]-oxetane

Guidance literature:: With 1H-imidazole; In dichloromethane; at 0 - 20 ℃; for 22h; Inert atmosphere;
DOI:10.1016/j.bmc.2013.06.032

Reference yield:

: 1450912-10-3
3-[(4-methoxybenzyloxy)methyl]-oxetan-3-ylmethanol

: 1450912-13-6
3-{1-[(tert-butyldimethylsilyl)oxy]prop-2-enyl}-3-[(4-methoxybenzyloxy)methyl]-oxetane

Guidance literature:: Multi-step reaction with 3 steps

1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.67 h / -78 °C / Inert atmosphere

1.2: 0.83 h / -78 - 0 °C / Inert atmosphere

2.1: tetrahydrofuran; toluene / 0.58 h / -78 °C / Inert atmosphere

3.1: 1H-imidazole / dichloromethane / 22 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; oxalyl dichloride; dimethyl sulfoxide; In tetrahydrofuran; dichloromethane; toluene; 1.1: |Swern Oxidation / 1.2: |Swern Oxidation;
DOI:10.1016/j.bmc.2013.06.032

Reference yield:

: 1450912-11-4
3-[(4-methoxybenzyloxy)methyl]-oxetane-3-carbaldehyde

: 1450912-13-6
3-{1-[(tert-butyldimethylsilyl)oxy]prop-2-enyl}-3-[(4-methoxybenzyloxy)methyl]-oxetane

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran; toluene / 0.58 h / -78 °C / Inert atmosphere

2: 1H-imidazole / dichloromethane / 22 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1016/j.bmc.2013.06.032