5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarbaldehyde

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Chemical Name:5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarbaldehyde
CAS No.:152428-94-9
Molecular Formula:C₁₅H₁₄O₂
Molecular Weight:226.275
Hs Code.:

Synonyms:5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarbaldehyde

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Chemical Property of 5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarbaldehyde

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Technology Process of 5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarbaldehyde

There total 5 articles about 5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 152428-93-8
[5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienyl]-methanol

: 152428-94-9
5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarbaldehyde

Guidance literature:: With tris(triphenylphosphine)ruthenium(II) chloride; 4-methylmorpholine N-oxide; In acetone; at 20 ℃; for 0.333333h; Yield given;

Reference yield:

: 152428-88-1
4-Methyl-4-((Z)-6-trimethylsilanyl-hex-3-ene-1,5-diynyl)-cyclohex-2-enone

: 152428-94-9
5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarbaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) LiHMDS, 2.) HMPA

2: NaH / tetrahydrofuran; hexamethylphosphoric acid triamide / 0.83 h / -78 - -10 °C

3: (nBu)4NF*(H₂O)x, K₂CO₃ / tetrahydrofuran / 0.08 h / 0 °C

4: DIBAL / toluene / 0.67 h / -16 °C

5: RuCl₂(PPh₃)3, N-methylmorpholine N-oxide / acetone / 0.33 h / 20 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; tris(triphenylphosphine)ruthenium(II) chloride; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; potassium carbonate; 4-methylmorpholine N-oxide; lithium hexamethyldisilazane; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; acetone; toluene;

Reference yield:

: 152428-92-7
5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarboxylic acid methyl ester

: 152428-94-9
5-((Z)-Hex-3-ene-1,5-diynyl)-2-methoxy-5-methyl-cyclohexa-1,3-dienecarbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: DIBAL / toluene / 0.67 h / -16 °C

2: RuCl₂(PPh₃)3, N-methylmorpholine N-oxide / acetone / 0.33 h / 20 °C

With tris(triphenylphosphine)ruthenium(II) chloride; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; In acetone; toluene;