4-(1-vinyl-1-hydroperoxycyclohex-1-yl)-2-butanone tert-butyldimethylsilyl ether

Base Information

Chemical Name:4-(1-vinyl-1-hydroperoxycyclohex-1-yl)-2-butanone tert-butyldimethylsilyl ether
CAS No.:96165-26-3
Molecular Formula:C₁₈H₃₄O₃Si
Molecular Weight:326.552
Hs Code.:

Synonyms:4-(1-vinyl-1-hydroperoxycyclohex-1-yl)-2-butanone tert-butyldimethylsilyl ether

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Chemical Property of 4-(1-vinyl-1-hydroperoxycyclohex-1-yl)-2-butanone tert-butyldimethylsilyl ether

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Technology Process of 4-(1-vinyl-1-hydroperoxycyclohex-1-yl)-2-butanone tert-butyldimethylsilyl ether

There total 5 articles about 4-(1-vinyl-1-hydroperoxycyclohex-1-yl)-2-butanone tert-butyldimethylsilyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 96165-25-2
4-(2-Hydroperoxy-2-vinyl-cyclohexyl)-butan-2-one

: 96165-26-3
4-(1-vinyl-1-hydroperoxycyclohex-1-yl)-2-butanone tert-butyldimethylsilyl ether

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 9h; Ambient temperature;
DOI:10.1021/jo00211a047

Reference yield:

: 10407-33-7,58769-44-1
methyl 3-(2-oxocyclohexyl)propionate

: 96165-26-3
4-(1-vinyl-1-hydroperoxycyclohex-1-yl)-2-butanone tert-butyldimethylsilyl ether

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) NaH, DMSO / 1.) RT, 2.) RT, 1 h

2: 100 percent / 85 percent KOH / methanol / 24 h / Ambient temperature

3: 87 percent / diethyl ether / 24 h / Ambient temperature

4: 81 percent / oxygen, rose bengal / acetonitrile / 1.5 h / Irradiation

5: 99 percent / imidazole / dimethylformamide / 9 h / Ambient temperature

With 1H-imidazole; potassium hydroxide; oxygen; rose bengal; sodium hydride; dimethyl sulfoxide; In methanol; diethyl ether; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo00211a047

Reference yield:

: 96165-23-0
4-(1-ethylidenecyclohex-2-yl)2-butanone

: 96165-26-3
4-(1-vinyl-1-hydroperoxycyclohex-1-yl)-2-butanone tert-butyldimethylsilyl ether

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / oxygen, rose bengal / acetonitrile / 1.5 h / Irradiation

2: 99 percent / imidazole / dimethylformamide / 9 h / Ambient temperature

With 1H-imidazole; oxygen; rose bengal; In N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo00211a047