1-(4-chloro-2-nitro)phenoxy-11-(2-bromo-4-chloro)phenoxy-3,6,9-trioxaundecane

Base Information

• Chemical Name: 1-(4-chloro-2-nitro)phenoxy-11-(2-bromo-4-chloro)phenoxy-3,6,9-trioxaundecane
• CAS No.: 177713-13-2
• Molecular Formula: C₂₀H₂₂BrCl₂NO₇
• Molecular Weight: 539.207
• Mol file: 177713-13-2.mol

Synonyms:1-(4-chloro-2-nitro)phenoxy-11-(2-bromo-4-chloro)phenoxy-3,6,9-trioxaundecane

Chemical Property of 1-(4-chloro-2-nitro)phenoxy-11-(2-bromo-4-chloro)phenoxy-3,6,9-trioxaundecane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(4-chloro-2-nitro)phenoxy-11-(2-bromo-4-chloro)phenoxy-3,6,9-trioxaundecane

There total 4 articles about 1-(4-chloro-2-nitro)phenoxy-11-(2-bromo-4-chloro)phenoxy-3,6,9-trioxaundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2-bromo-4-chlorophenol (695-96-5) + 1-methansulfonyloxy-11-(4-chloro-2-nitro)phenoxy-3,6,9-trioxaundecane (177713-12-1) → 1-(4-chloro-2-nitro)phenoxy-11-(2-bromo-4-chloro)phenoxy-3,6,9-trioxaundecane (177713-13-2)

Guidance literature:

With sodium hydroxide; In butan-1-ol; for 3h; Heating;

DOI:10.1016/0040-4020(96)00285-2

Reference yield:

Tetraethylene glycol (112-60-7) → 1-(4-chloro-2-nitro)phenoxy-11-(2-bromo-4-chloro)phenoxy-3,6,9-trioxaundecane (177713-13-2)

Guidance literature:

Multi-step reaction with 3 steps

1: 85 percent / Na / 3 h / 110 °C

2: 97 percent / pyridine / CHCl₃ / 3 h / Ambient temperature

3: 80 percent / aq. NaOH / butan-1-ol / 3 h / Heating

With pyridine; sodium hydroxide; sodium; In chloroform; butan-1-ol;

DOI:10.1016/0040-4020(96)00285-2

Reference yield:

1-hydroxy-11-(4-chloro-2-nitro)phenoxy-3,6,9-trioxaundecane (177713-11-0) → 1-(4-chloro-2-nitro)phenoxy-11-(2-bromo-4-chloro)phenoxy-3,6,9-trioxaundecane (177713-13-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 97 percent / pyridine / CHCl₃ / 3 h / Ambient temperature

2: 80 percent / aq. NaOH / butan-1-ol / 3 h / Heating

With pyridine; sodium hydroxide; In chloroform; butan-1-ol;

DOI:10.1016/0040-4020(96)00285-2

upstream raw materials:

2-bromo-4-chlorophenol

1-methansulfonyloxy-11-(4-chloro-2-nitro)phenoxy-3,6,9-trioxaundecane

Tetraethylene glycol

1-hydroxy-11-(4-chloro-2-nitro)phenoxy-3,6,9-trioxaundecane

Downstream raw materials:

N-{2-[2-(2-{2-[2-(2-Bromo-4-chloro-phenoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-5-chloro-phenyl}-formamide